Microstructural and dynamical heterogeneities in ionic liquids
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …
molecular symmetry and charge delocalization. The versatility in combining varied cation …
Recent advance in ionic‐liquid‐based electrolytes for rechargeable metal‐ion batteries
W Zhou, M Zhang, X Kong, W Huang… - Advanced …, 2021 - Wiley Online Library
From basic research to industry process, battery energy storage systems have played a
great role in the informatization, mobility, and intellectualization of modern human society …
great role in the informatization, mobility, and intellectualization of modern human society …
Perspectives for polymer electrolytes: a view from fundamentals of ionic conductivity
We present a brief overview of current developments in the field of polymer electrolytes, with
the focus on single-ion conducting polymers. The latter have significant advantages relative …
the focus on single-ion conducting polymers. The latter have significant advantages relative …
Direct evidence for Li ion hop** conduction in highly concentrated sulfolane-based liquid electrolytes
We demonstrate that Li+ hop** conduction, which cannot be explained by conventional
models ie, Onsager's theory and Stokes' law, emerges in highly concentrated liquid …
models ie, Onsager's theory and Stokes' law, emerges in highly concentrated liquid …
Dynamic ion correlations in solid and liquid electrolytes: how do they affect charge and mass transport?
Solid and liquid electrolytes for electrochemical energy storage and conversion cells, such
as batteries, supercapacitors and fuel cells, contain often high concentrations of mobile ions …
as batteries, supercapacitors and fuel cells, contain often high concentrations of mobile ions …
Superionicity in ionic-liquid-based electrolytes induced by positive ion–ion correlations
In ionic-liquid (IL)-based electrolytes, relevant for current energy storage applications, ion
transport is limited by strong ion–ion correlations, generally yielding inverse Haven ratios …
transport is limited by strong ion–ion correlations, generally yielding inverse Haven ratios …
Coordination Effects in Polymer Electrolytes: Fast Li+ Transport by Weak Ion Binding
MP Rosenwinkel, R Andersson… - The Journal of …, 2020 - ACS Publications
In view of the limited ionic conductivity and low lithium transference number in classical poly
(ethylene oxide)(PEO)-based salt-in-polymer electrolytes, employing alternative polymer …
(ethylene oxide)(PEO)-based salt-in-polymer electrolytes, employing alternative polymer …
A volume-based description of transport in incompressible liquid electrolytes and its application to ionic liquids
F Kilchert, M Lorenz, M Schammer… - Physical Chemistry …, 2023 - pubs.rsc.org
Transference numbers play an important role in understanding the dynamics of electrolytes
and assessing their performance in batteries. Unfortunately, these transport parameters are …
and assessing their performance in batteries. Unfortunately, these transport parameters are …
Water-In-Salt LiTFSI Aqueous Electrolytes (2): Transport Properties and Li+ Dynamics Based on Molecular Dynamics Simulations
The transport properties of water-in-salt lithium bis (trifluoromethane sulfonyl) imide (LiTFSI)
aqueous electrolytes were studied using classical molecular dynamics (MD) simulations. At …
aqueous electrolytes were studied using classical molecular dynamics (MD) simulations. At …
How do super concentrated electrolytes push the Li-ion batteries and supercapacitors beyond their thermodynamic and electrochemical limits?
Increasing the energy density of energy storage devices is currently the key target of many
battery and supercapacitor research activities. For both types of devices, the electrochemical …
battery and supercapacitor research activities. For both types of devices, the electrochemical …