Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching,“Cocktails” of catalysts and dynamic systems

DB Eremin, VP Ananikov - Coordination Chemistry Reviews, 2017 - Elsevier
In the present review, we consider the transformations of molecular catalysts, leaching,
aggregation and various interconversions of metal complexes, clusters and nanoparticles …

Metal–organic frameworks catalyzed C–C and C–heteroatom coupling reactions

A Dhakshinamoorthy, AM Asiri, H Garcia - Chemical Society Reviews, 2015 - pubs.rsc.org
Metal organic frameworks (MOFs) are porous crystalline solids whose structure is formed by
metal ions or clusters of a few metal ions held in place by bi-or multipodal organic linkers. In …

Phantom reactivity in organic and catalytic reactions as a consequence of microscale destruction and contamination-trap** effects of magnetic stir bars

EO Pentsak, DB Eremin, EG Gordeev… - ACS catalysis, 2019 - ACS Publications
Magnetic stir bars are routinely used by every chemist doing synthetic or catalytic
transformations in solution. Each bar lasts for months or years, as the regular PTFE …

Alleviating the self-discharge and enhancing the polysulphides conversion kinetics with LaCO3OH nanocrystals decorated hierarchical porous carbon

Y Lin, W Tang, S Wu, Y Zhang, Z Kong, C Shen… - Chemical Engineering …, 2023 - Elsevier
Abstract Lithium-sulfur (Li-S) batteries have been recognized as one of the most promising
energy storage devices due to their ultrahigh energy density of 2600 Wh kg− 1. However …

Phosphorus doped hierarchical porous carbon nanosheet array as an electrocatalyst to enhance polysulfides anchoring and conversion

Z Kong, Y Lin, J Hu, Y Wang, L Zhan - Chemical Engineering Journal, 2022 - Elsevier
The sluggish redox kinetics and severe lithium polysulfides (LiPSs) shutting effect in lithium
sulfur batteries (LSBs) greatly hinder their practical applications. In this work, phosphorus …

Catalyst enhancement and recyclability by immobilization of metal complexes onto graphene surface by noncovalent interactions

S Sabater, JA Mata, E Peris - Acs Catalysis, 2014 - ACS Publications
The immobilization of a homogeneous catalyst onto a solid surface is one of the major
challenges in catalysis, because it may facilitate the separation of the catalyst and the …

Coordination chemistry on carbon surfaces

MR Axet, O Dechy-Cabaret, J Durand… - Coordination Chemistry …, 2016 - Elsevier
Immobilization of transition metal complexes with catalytic, electronic or luminescent
properties onto solid supports is a theme of intense research. The relatively good knowledge …

Modified nanocarbons for catalysis

V Campisciano, M Gruttadauria, F Giacalone - ChemCatChem, 2019 - Wiley Online Library
Nanocarbons represent useful scaffolds in the preparation of last generation nanostructured
catalysts, and their chemical functionalization through covalent or non‐covalent modification …

The pivotal role of the counterion in gold catalyzed hydration and alkoxylation of alkynes

D Zuccaccia, A Del Zotto, W Baratta - Coordination Chemistry Reviews, 2019 - Elsevier
Hydration and alkoxylation of alkynes are key processes for the industrial production of
carbonyl derivatives. In this review, the pivotal role of ion pairing in the mechanism of …

Gold (I) Complexes with Eight‐Membered NHC Ligands: Synthesis, Structures and Catalytic Activity

A Cervantes‐Reyes, F Rominger… - Advanced Synthesis …, 2020 - Wiley Online Library
A series of expanded‐ring NHC gold complexes of the formula (NaphtDHD− Ar) Au− X
(NaphtDHD= 4, 5‐dihydro‐1H‐naphtho [1, 8‐ef][1, 3] diazocin‐3 (2H)‐ylidene; Ar: Mes= 2, 4 …