Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Transition-metal catalyzed C–H activation as a means of synthesizing complex natural products

SK Sinha, P Ghosh, S Jain, S Maiti… - Chemical Society …, 2023 - pubs.rsc.org
Over the past few decades, the advent of C–H activation has led to a rethink among
chemists about the synthetic strategies employed for multi-step transformations. Indeed …

Expanding chemistry through in vitro and in vivo biocatalysis

EN Kissman, MB Sosa, DC Millar, EJ Koleski… - Nature, 2024 - nature.com
Living systems contain a vast network of metabolic reactions, providing a wealth of enzymes
and cells as potential biocatalysts for chemical processes. The properties of protein and cell …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Catalytic dehydrogenative cross-coupling: forming carbon− carbon bonds by oxidizing two carbon− hydrogen bonds

CS Yeung, VM Dong - Chemical reviews, 2011 - ACS Publications
Inspired by the need for green and sustainable chemistry,(1) synthetic chemists seek more
efficient ways to construct carbon− carbon (C− C) bonds, the essential link in all organic …

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

L McMurray, F O'Hara, MJ Gaunt - Chemical Society Reviews, 2011 - pubs.rsc.org
Metal-catalysed C–H bond functionalisation has had a significant impact on how chemists
make molecules. Translating the methodological developments to their use in the assembly …

C–H functionalization logic in total synthesis

WR Gutekunst, PS Baran - Chemical Society Reviews, 2011 - pubs.rsc.org
In this critical review, the strategic and economic benefits of C–H functionalization logic will
be analyzed through the critical lens of total synthesis. In order to illustrate the dramatically …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Palladium‐catalyzed cross‐coupling reactions in total synthesis

KC Nicolaou, PG Bulger… - Angewandte Chemie …, 2005 - Wiley Online Library
In studying the evolution of organic chemistry and gras** its essence, one comes quickly
to the conclusion that no other type of reaction plays as large a role in sha** this domain …

C H Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

DYK Chen, SW Youn - Chemistry–A European Journal, 2012 - Wiley Online Library
The recent advent of transition‐metal mediated C H activation is revolutionizing the
synthetic field and gradually infusing a “C H activation mind‐set” in both students and …