Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Atom transfer radical polymerization (ATRP): current status and future perspectives

K Matyjaszewski - Macromolecules, 2012 - ACS Publications
Current status and future perspectives in atom transfer radical polymerization (ATRP) are
presented. Special emphasis is placed on mechanistic understanding of ATRP, recent …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis

N Zhang, SR Samanta, BM Rosen, V Percec - Chemical Reviews, 2014 - ACS Publications
The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

C H Bond Activation in Transition Metal Species from a Computational Perspective

D Balcells, E Clot, O Eisenstein - Chemical reviews, 2010 - ACS Publications
Alkanes constitute the cheapest and most abundant feedstock for organic chemicals.
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …

Evolution and future directions of metal-free atom transfer radical polymerization

EH Discekici, A Anastasaki, J Read de Alaniz… - …, 2018 - ACS Publications
The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond
traditional polymer science has necessitated the development of alternative strategies for …

“Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials

NV Tsarevsky, K Matyjaszewski - Chemical reviews, 2007 - ACS Publications
Virtually every branch of science, technology, and art uses a plethora of polymeric materials.
These include not only “pure” linear, branched, or cross-linked (gels, rubbers, etc.) polymers …