Tetravalent Cerium Alkyl and Benzyl Complexes
High-valent cerium complexes of alkyl and benzyl ligands are unprecedented due to the
incompatibility of the typically highly oxidizing Ce4+ ion and the reducing alkyl or benzyl …
incompatibility of the typically highly oxidizing Ce4+ ion and the reducing alkyl or benzyl …
Ligand control of oxidation and crystallographic disorder in the isolation of hexavalent uranium mono-oxo complexes
The development of high-valent transuranic chemistry requires robust methodologies to
access and fully characterize reactive species. We have recently demonstrated that the …
access and fully characterize reactive species. We have recently demonstrated that the …
In Crystallo O2 Cleavage at a Preorganized Triiron Cluster
In Nature, the four-electron reduction of O2 is catalyzed at preorganized multimetallic active
sites. These complex active sites often feature low-coordinate, redox-active metal centers …
sites. These complex active sites often feature low-coordinate, redox-active metal centers …