Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

Natural products possess structural complexity, diversity and chirality with attractive
functions and biological activities that have significantly impacted drug discovery initiatives …

Upon irradiation in the presence of a chiral benzophenone catalyst (5 mol%), a racemic
mixture of a given chiral imidazolidine-2, 4-dione (hydantoin) can be converted almost …

Isomerizations are chemical processes where a compound is transformed into another
structure while retaining the same chemical formula. When dynamic, these reactions are …

In the present manuscript, a series of Ni (II), Cu (II) and Zn (II) based metal complexes were
synthesized, and their molecular geometry was established using single‐crystal X‐ray …

Chirality plays a critical role in the biochemistry of life and often only one enantiomeric series
is observed (homochirality). Only a few natural products have been obtained as racemates …

A sequence involving photocatalytic hydrogen atom transfer (HAT), reductive radical-polar
crossover (RRPCO), and protonation/deuteration for stereochemical editing at benzylic …

Parkinson's Disease (PD) is a progressive neurodegenerative disorder with a long
prodromal course. Most cases are sporadic but a polygenic risk score (PRS) recently …

Racemases and epimerases catalyse changes in the stereochemical configurations of chiral
centres and are of interest as model enzymes and as biotechnological tools. They also …

Diastereomers are characterised by an intrinsic energy difference, and thermodynamics
dictate their distribution within a dynamic equilibrium. The characteristic mechanistic …