Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R **, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Ultrasmall coinage metal nanoclusters as promising theranostic probes for biomedical applications

G Yang, Z Wang, F Du, F Jiang, X Yuan… - Journal of the American …, 2023 - ACS Publications
Ultrasmall coinage metal nanoclusters (NCs,< 3 nm) have emerged as a novel class of
theranostic probes due to their atomically precise size and engineered physicochemical …

Tailoring the photoluminescence of atomically precise nanoclusters

X Kang, M Zhu - Chemical Society Reviews, 2019 - pubs.rsc.org
Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Total Structure, Electronic Structure and Catalytic Hydrogenation Activity of Metal‐Deficient Chiral Polyhydride Cu57 Nanoclusters

GG Luo, ZH Pan, BL Han, GL Dong… - Angewandte Chemie …, 2023 - Wiley Online Library
Accurate identifying and in‐depth understanding of the defect sites in a working
nanomaterial could hinge on establishing specific defect‐activity relationships. Yet …

Isostructural nanocluster manipulation reveals pivotal role of one surface atom in click chemistry

C Dong, RW Huang, A Sagadevan… - Angewandte Chemie …, 2023 - Wiley Online Library
Elucidating single‐atom effects on the fundamental properties of nanoparticles is
challenging because single‐atom modifications are typically accompanied by appreciable …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Correlations between the fundamentals and applications of ultrasmall metal nanoclusters: Recent advances in catalysis and biomedical applications

Z Liu, Z Wu, Q Yao, Y Cao, OJH Chai, J **e - Nano Today, 2021 - Elsevier
Ultrasmall metal nanoparticles (NPs) with a well-defined composition and structure, the so-
called metal nanoclusters (NCs, usually smaller than 3 nm in size), represent the forefront …

Origin of the photoluminescence of metal nanoclusters: from metal-centered emission to ligand-centered emission

TQ Yang, B Peng, BQ Shan, YX Zong, JG Jiang, P Wu… - Nanomaterials, 2020 - mdpi.com
Recently, metal nanoclusters (MNCs) emerged as a new class of luminescent materials and
have attracted tremendous interest in the area of luminescence-related applications due to …

Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …