Mechanochemical tools for polymer materials
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …
failure and healing of polymer materials. The development of mechanophores–molecular …
The many flavours of mechanochemistry and its plausible conceptual underpinnings
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
The role of polymer mechanochemistry in responsive materials and additive manufacturing
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
Azobenzene as a photoswitchable mechanophore
Azobenzene has been widely explored as a photoresponsive element in materials science.
Although some studies have investigated the force-induced isomerization of azobenzene …
Although some studies have investigated the force-induced isomerization of azobenzene …
Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Validation of the CoGEF method as a predictive tool for polymer mechanochemistry
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …
component of the field of polymer mechanochemistry. Mechanophores enable the design …
Rotaxanes as mechanochromic fluorescent force transducers in polymers
The integration of mechanophores, motifs that transduce mechanical forces into chemical
reactions, allows creating materials with stress-dependent properties. Typical …
reactions, allows creating materials with stress-dependent properties. Typical …
Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
Twisted aggregation-induced emission luminogens (AIEgens) contribute to mechanochromism materials: a review
Y Sun, Z Lei, H Ma - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
Mechanochromic luminescence (MCL) materials, which are stimulated by mechanical force,
have several promising advantages, such as controllable stimulus response, reversible …
have several promising advantages, such as controllable stimulus response, reversible …
Harnessing the power of force: development of mechanophores for molecular release
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …
materials for a variety of applications ranging from sensing and catalysis to targeted drug …