Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes

R Maity, B Sarkar - JACS au, 2021 - ACS Publications
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Metal Complexes of Click‐Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

D Schweinfurth, L Hettmanczyk… - … für anorganische und …, 2017 - Wiley Online Library
Even though the existence of 1, 2, 3‐triazoles has been known for more than a century, the
recent discovery of a copper (I) catalyzed version of this reaction has attributed …

A Different Perspective on Tuning the Photophysical and Photochemical Properties: The Influence of Constitutional Isomers in Group 6 Carbonyl Complexes with …

T Bens, D Marhöfer, P Boden, ST Steiger… - Inorganic …, 2023 - ACS Publications
Exploring novel and existing design principles to tune the photochemical and photophysical
properties of transition-metal complexes is an important goal in contemporary research …

Photophysics and photochemistry of 1, 2, 3-triazole-based complexes

PA Scattergood, A Sinopoli, PIP Elliott - Coordination Chemistry Reviews, 2017 - Elsevier
The copper-catalysed cycloaddition of alkynes and azides to form 1, 2, 3-triazoles has
emerged as a powerful tool in ligand design and the synthesis of novel transition metal …

Heteromultimetallic Complexes with Redox‐Active Mesoionic Carbenes: Control of Donor Properties and Redox‐Induced Catalysis

L Hettmanczyk, L Suntrup, S Klenk… - … A European Journal, 2017 - Wiley Online Library
Mesoionic carbenes (MICs) are currently hugely popular as ligands, and triazolylidenes are
arguably the most prominent classes of such MICs. Mesoionic carbenes with ferrocenyl …

NIR‐Emissive Chromium (0), Molybdenum (0), and Tungsten (0) Complexes in the Solid State at Room Temperature

P Boden, P Di Martino‐Fumo, T Bens… - … A European Journal, 2021 - Wiley Online Library
The development of NIR emitters based on earth‐abundant elements is an important goal in
contemporary science. We present here Cr (0), Mo (0), and W (0) carbonyl complexes with a …

Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction

L Suntrup, F Stein, J Klein, A Wilting… - Inorganic …, 2020 - ACS Publications
Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …

Gauging donor/acceptor properties and redox stability of chelating click-derived triazoles and triazolylidenes: a case study with rhenium (I) complexes

L Suntrup, S Klenk, J Klein, S Sobottka… - Inorganic …, 2017 - ACS Publications
Bidentate ligands containing at least one triazole or triazolylidene (mesoionic carbene, MIC)
unit are extremely popular in contemporary chemistry. One reason for their popularity is the …

[HTML][HTML] Recent advances in the development of the btp motif: A versatile terdentate coordination ligand for applications in supramolecular self-assembly, cation and …

AF Henwood, IN Hegarty, EP McCarney, JI Lovitt… - Coordination Chemistry …, 2021 - Elsevier
Abstract The btp [2, 6-bis (1, 2, 3-triazol-4-yl) pyridine] ligand is a terdentate ligand that,
analogously to many other terdentate ligands such as 2, 2′; 6, 2 ″-terpyridine (terpy), has …