Selective catalytic reduction of NOx with NH3: opportunities and challenges of Cu-based small-pore zeolites

Y Shan, J Du, Y Zhang, W Shan, X Shi… - National science …, 2021 - academic.oup.com
Zeolites, as efficient and stable catalysts, are widely used in the environmental catalysis
field. Typically, Cu-SSZ-13 with small-pore structure shows excellent catalytic activity for …

Recent advances in hybrid metal oxide–zeolite catalysts for low-temperature selective catalytic reduction of NOx by ammonia

T Andana, KG Rappe, F Gao, J Szanyi… - Applied Catalysis B …, 2021 - Elsevier
A hybrid catalytic system comprised of metal oxide and Cu or Fe exchanged zeolite
components represents a potential advancement of state-of-the-art for selective catalytic …

Interface Engineering of a Bifunctional Cu-SSZ-13@CZO Core–Shell Catalyst for Boosting Potassium Ion and SO2 Tolerance

L Jia, J Liu, D Huang, J Zhao, J Zhang, K Li, Z Li… - ACS …, 2022 - ACS Publications
The poisoning of sulfur oxides and alkali metals emitted from diesel exhaust to active sites of
copper ion-exchanged chabazite (Cu-CHA) catalysts is still present and remains a …

Comparative analysis of the dual origins of the N 2 O byproduct on MnO x, FeO x, and MnFeO x sphere catalysts for a low-temperature SCR of NO with NH 3

Z Chen, R Guo, S Ren, L Chen, X Li… - Journal of Materials …, 2022 - pubs.rsc.org
Herein, the origin and evolution mechanism of N2O formation over the MnFeOx spherical
catalyst were investigated in detail, accompanied by a comparison analysis of pristine MnOx …

Interplay between copper redox and transfer and support acidity and topology in low temperature NH3-SCR

Y Wu, W Zhao, SH Ahn, Y Wang, ED Walter… - Nature …, 2023 - nature.com
Low-temperature standard NH3-SCR over copper-exchanged zeolite catalysts occurs on
NH3-solvated Cu-ion active sites in a quasi-homogeneous manner. As key kinetically …

Recent progress in the improvement of hydrothermal stability of zeolites

R Simancas, A Chokkalingam, SP Elangovan, Z Liu… - Chemical …, 2021 - pubs.rsc.org
Zeolites have been successfully employed in many catalytic reactions of industrial
relevance. The severe conditions required in some processes, where high temperatures are …

Recent progress of metal-exchanged zeolites for selective catalytic reduction of NOx with NH3 in diesel exhaust

X Wang, Y Xu, Z Zhao, J Liao, C Chen, Q Li - Fuel, 2021 - Elsevier
In recent years, selective catalytic reduction (SCR) with NH 3 technology has been
extensively applied in the removal of nitrogen oxide (NO x) from diesel exhaust due to its …

Activating low-temperature NH3-SCR catalyst by breaking the strong interface between acid and redox sites: A case of model Ce2 (SO4) 3-CeO2 study

J Ji, M **g, X Wang, W Tan, K Guo, L Li, X Wang… - Journal of …, 2021 - Elsevier
The occurrence of NH 3-SCR (selective catalytic reduction of NO with NH 3) reaction on
catalyst surface typically requires acid and redox sites. However, the role of acid-redox …

Efficient and selective dual-pathway polyolefin hydro-conversion over unexpectedly bifunctional M/TiO2-anatase catalysts

L Chen, JB Moreira, LC Meyer, J Szanyi - Applied Catalysis B …, 2023 - Elsevier
The huge scale of plastic waste generation and its environmental consequences drive the
demands for catalytic plastic upcycling processes. Here, we report efficient polypropylene …

Probing active-site relocation in Cu/SSZ-13 SCR catalysts during hydrothermal aging by in situ EPR spectroscopy, kinetics studies, and DFT calculations

Y Zhang, Y Peng, J Li, K Groden, JS McEwen… - ACS …, 2020 - ACS Publications
Cu/SSZ-13 selective catalytic reduction catalysts display activity loss after mild hydrothermal
aging without support degradation or loss of isolated Cu cation content. By applying electron …