Six-membered heterocycles containing one phosphorus and one nitrogen atom, known as
azaphosphinines, have existed in the shadows of their single heteroatom-containing …

This review covers the progress that has been made during the last 10 years in the
coordination chemistry of 1-phosphinines, 1, 4-diphosphinines and 1, 3, 5-triphosphinines …

π-Extended molecules based on six-membered phosphorus heterocycles are exceptional
systems due to their unique structural and chemical properties. Even though the first six …

The manipulation of the photophysical properties of molecular emitters can be realized by
composing the close environment of the metal center with the “heavier pnictogen atom” …

A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both
in solution and solid state, is described. Both C4-selective electrophilic substitutions and the …

Abstract The [4+ 2] cycloaddition reaction between 2‐pyrone and Me3Si− C≡ P gives the
corresponding 2‐(trimethylsilyl)‐λ3‐phosphinine in good yields as a rather air and moisture …

This microreview describes progress in the development and coordination chemistry of
donor‐functionalized phosphinines–the phosphorus analogues of pyridines–that has been …

New efficient redox flow batteries (RFBs) are currently of great interest for large-scale
storage of renewable energy. Further development requires the improvement of the redox …

π-Conjugated organophosphorus derivatives have recently emerged as valuable building
blocks for the tailoring of functional molecular materials. We have focused for ten years on …

Phosphinines belong to an intriguing class of phosphorus-containing heterocycles with
interesting steric, electronic and coordinating properties. This article focuses on recent …