Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions
E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
[HTML][HTML] Stimuli-responsive synthetic helical polymers
M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …
helix as a structural motif. Although the materials are different, these systems also share …
Helical polymers: synthesis, structures, and functions
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
Emerging chirality in nanoscience
Chirality in nanoscience may offer new opportunities for applications beyond the traditional
fields of chirality, such as the asymmetric catalysts in the molecular world and the chiral …
fields of chirality, such as the asymmetric catalysts in the molecular world and the chiral …
Chiral nanoarchitectonics: towards the design, self‐assembly, and function of nanoscale chiral twists and helices
Helical structures such as double helical DNA and the α‐helical proteins found in biological
systems are among the most beautiful natural structures. Chiral nanoarchitectonics, which is …
systems are among the most beautiful natural structures. Chiral nanoarchitectonics, which is …
Supramolecular Assemblies from Poly (phenylacetylene) s
The evolution of chemistry in the last 60 years can be illustrated by the introduction of just a
few new concepts. One is macromolecules,(1, 2) whose importance was recognized in the …
few new concepts. One is macromolecules,(1, 2) whose importance was recognized in the …
Control of One-Handed Helicity in Polyacetylenes: Impact of an Extremely Small Amount of Chiral Substituents
T Ikai, Y Morita, T Majima, S Takeda… - Journal of the …, 2023 - ACS Publications
Controlling the one-handed helicity in synthetic polymers is crucial for develo** helical
polymer-based advanced chiral materials. We now report that an extremely small amount of …
polymer-based advanced chiral materials. We now report that an extremely small amount of …
Solvent polarity driven helicity inversion and circularly polarized luminescence in chiral aggregation induced emission fluorophores
Q Ye, F Zheng, E Zhang, HK Bisoyi, S Zheng… - Chemical …, 2020 - pubs.rsc.org
Development of functional materials capable of exhibiting chirality tunable circularly
polarized luminescence (CPL) is currently in high demand for potential technological …
polarized luminescence (CPL) is currently in high demand for potential technological …
Helical polymers with dynamic and static macromolecular helicity memory: The power of helicity memory for helical polymer synthesis and applications
E Yashima, K Maeda - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
In this Account, we describe the recent progress in the synthesis and unique features and
functions of helical polymers with a controlled handedness based on the noncovalent …
functions of helical polymers with a controlled handedness based on the noncovalent …
Single-and double-stranded helical polymers: synthesis, structures, and functions
E Yashima, K Maeda, Y Furusho - Accounts of chemical research, 2008 - ACS Publications
Biological macromolecules, such as DNA and proteins, possess a unique and specific
ordered structure, such as a right-handed double helix or a single α-helix. Those structures …
ordered structure, such as a right-handed double helix or a single α-helix. Those structures …