Understanding deNO x mechanisms in transition metal exchanged zeolites

JA Nasir, AM Beale, CRA Catlow - Chemical Society Reviews, 2024 - pubs.rsc.org
Transition-metal-containing zeolites have wide-ranging applications in several catalytic
processes including the selective catalytic reduction (SCR) of NOx species. To understand …

Nitrous oxide production from wastewater treatment: The potential as energy resource rather than potent greenhouse gas

L Wu, L Peng, W Wei, D Wang, BJ Ni - Journal of hazardous materials, 2020 - Elsevier
Abstract Nitrous oxide (N 2 O), produced from wastewater treatment, is a potent greenhouse
gas and has become a global concern in recent years. However, N 2 O has also been …

Quasicatalytic and catalytic oxidation of methane to methanol by nitrous oxide over FeZSM-5 zeolite

MV Parfenov, EV Starokon, LV Pirutko, GI Panov - Journal of Catalysis, 2014 - Elsevier
Methane oxidation by N 2 O at 200° C and below was shown to proceed in a quasicatalytic
mode resulting in product accumulation on FeZSM-5 surface. Methanol that formed via …

N2O decomposition over Fe-zeolites: Structure of the active sites and the origin of the distinct reactivity of Fe-ferrierite, Fe-ZSM-5, and Fe-beta. A combined periodic …

S Sklenak, PC Andrikopoulos, B Boekfa, B Jansang… - Journal of …, 2010 - Elsevier
The N2O decomposition over Fe-ferrierite, Fe-beta, and Fe-ZSM-5 has been recently studied
[K. Jisa, J. Novakova, M. Schwarze, A. Vondrova, S. Sklenak, Z. Sobalik, J. Catal. 262 (2009) …

Stability of extraframework iron-containing complexes in ZSM-5 zeolite

G Li, EA Pidko, RA Van Santen, C Li… - The Journal of …, 2013 - ACS Publications
The stability of oxygenated and hydroxylated iron complexes in Fe/ZSM-5 is studied by
periodic DFT calculations. The reaction paths for the interconversion of various potential iron …

Self-synthesis and performance analysis of a Cu-Fe composite ZSM-5 zeolitic catalyst for NOx reduction and particulate matter removal using NH3 SCR

S Shirke, FC Chou, YZ Wang, PC Cheng… - Journal of …, 2024 - Elsevier
The NH3-SCR has gained widespread usage due to its exceptional denitrification efficiency.
It achieves high nitrogen oxides (NOx) reduction rates within the temperature range of …

Stability and reactivity of active sites for direct benzene oxidation to phenol in Fe/ZSM-5: A comprehensive periodic DFT study

G Li, EA Pidko, RA Van Santen, Z Feng, C Li… - Journal of catalysis, 2011 - Elsevier
The stability of isolated extraframework Fe2+ ions in ZSM-5 zeolite and their reactivity in the
benzene to phenol oxidation were studied by periodic DFT calculations. Mononuclear iron …

Ethylene epoxidation with nitrous oxide over Fe–BTC metal–organic frameworks: a DFT study

T Maihom, S Choomwattana, S Wannakao… - …, 2016 - Wiley Online Library
The epoxidation of ethylene with N2O over the metal‐organic framework Fe–BTC (BTC= 1,
3, 5‐benzentricarboxylate) is investigated by means of density functional calculations. Two …

Interaction between Ru and Co3O4 for promoted catalytic decomposition of N2O over the Rux-Co3O4 catalysts

C Sui, T Zhang, Y Dong, F Yuan, X Niu, Y Zhu - Molecular Catalysis, 2017 - Elsevier
A serial of Rux-Co 3 O 4 (x= 0.1, 0.2 and 0.3) catalysts were prepared by the coprecipitation
method and applied to the decomposition of N 2 O. They were characterized by the XRD …

Embedded-cluster calculations in a numeric atomic orbital density-functional theory framework

D Berger, AJ Logsdail, H Oberhofer… - The Journal of …, 2014 - pubs.aip.org
We integrate the all-electron electronic structure code FHI-aims into the general ChemShell
package for solid-state embedding quantum and molecular mechanical (QM/MM) …