Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

During the past 15 years, an increasing number of research groups have embraced visible-
light-mediated synthetic transformations as a powerful strategy for the construction and …

β-(Hetero) arylethylamines are privileged structural motifs found in many high-value organic
molecules, including pharmaceuticals and natural products. To construct these important …

Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

Abstract The 1, 2-arylheteroaryl ethane motif stands as a privileged scaffold with promising
implications in drug discovery. Conventional de novo syntheses of these molecules have …

Highly strained 1, 3-disubstituted bicyclo [1.1. 1] pentanes (BCPs) have been established as
bioisosteres of para-disubstituted benzene because they impart valuable pharmacokinetic …

Radical addition reactions of olefins have emerged as an attractive tool for the rapid
assembly of complex structures, and have plentiful applications in organic synthesis …

The radical anion of CO2 (CO2•–) is a strongly nucleophilic radical species with rapidly
emerging applications in contemporary organic chemistry. This radical species exhibits high …

Utilization of oxime esters as bifunctional reagents in energy-transfer photocatalysis has
received considerable attention. However, the reaction type is so far limited to the …

Atomic carbon and its corresponding masked analogues are exceedingly underexplored
intermediates in synthesis. Despite this, these reagents possess inimitable reactivity such as …