Palladium Catalysis: Dependence of the Efficiency of C− C Bond Formation on Carboxylate Ligand and Alkali Metal Carboxylate or Carboxylic Acid Additive. Part A …

J Le Bras, J Muzart - Advanced Synthesis & Catalysis, 2023 - Wiley Online Library
A variety of Pd‐catalyzed reactions are carried out with palladium carboxylates in the
presence of carboxylic acids and/or alkali metal carboxylates. This review is Part A of three …

Strain-Release-Driven Phosphine and Rhodium Catalysis: Facile Synthesis of Unsymmetrical Tetrasubstituted Alkenes

J Zhang, Z Hu, L Qin, Y Gao, XQ Hu - ACS Catalysis, 2023 - ACS Publications
Tetrasubstituted alkenes are one of the most important classes of aggregation-induced
emission luminogens with wide applications in analytical chemistry, bioimaging science …

Synthesis of Quinoline-Based Pt–Sb Complexes with L-or Z-Type Interaction: Ligand-Controlled Redox via Anion Transfer

CK Webber, F Kong, J Kumawat, J Joy… - …, 2024 - ACS Publications
A series of Pt–Sb complexes with two or three L-type quinoline side arms were prepared
and studied. Two ligands, tri (8-quinolinyl) stibane (SbQ3, Q= 8-quinolinyl, 1) and 8, 8 …

Hexa-Fe (III) Carboxylate Complexes Facilitate Aerobic Hydrocarbon Oxidative Functionalization: Rh Catalyzed Oxidative Coupling of Benzene and Ethylene to Form …

MT Bennett, KA Park, CB Musgrave III… - ACS …, 2024 - ACS Publications
Fe (II) carboxylates react with dioxygen and carboxylic acid to form Fe6 (μ–OH) 2 (μ3–O) 2
(μ–X) 12 (HX) 2 (X= acetate or pivalate), which is an active oxidant for Rh-catalyzed arene …

Highly Anti-Markovnikov Selective Oxidative Arene Alkenylation Using Ir (I) Catalyst Precursors and Cu (II) Carboxylates

H Ketcham, W Zhu, TB Gunnoe - Organometallics, 2024 - ACS Publications
The Ir (I) complex [Ir (μ-Cl)(coe) 2] 2 (coe= cis-cyclooctene) is a catalyst precursor for
benzene alkenylation using Cu (II) carboxylate salts. Using [Ir (μ-Cl)(coe) 2] 2 …

Rhodium-Catalyzed Oxidative Alkenylation of Anisole: Control of Regioselectivity

CW Reid, TB Gunnoe - Organometallics, 2024 - ACS Publications
We report the conversion of anisoles and olefins to alkenyl anisoles via a transition-metal-
catalyzed arene C–H activation and olefin insertion mechanism. The catalyst precursor,[(η2 …

Rhodium-Catalyzed Arene Alkenylation: Selectivity and Reaction Mechanism as a Function of In Situ Oxidant Identity

MT Bennett, KA Park, TB Gunnoe - Organometallics, 2024 - ACS Publications
Rhodium catalyzed arene alkenylation reactions with arenes and olefins using dioxygen as
the direct oxidant (eg, ACS Catal. 2020, 10, 11519), Cu (II) carboxylates (eg, Science 2015 …

Selectivity Switch in Non‐Directed Palladium‐Catalyzed C− H Olefination of Chlorobenzene Derivatives

J Fichez, MI Lapuh, L Truong, H Oulyadi… - Advanced Synthesis …, 2024 - Wiley Online Library
A palladium (II)‐catalyzed oxidative C− H olefination of chlorobenzene derivatives, which
favored the functionalization at the ortho‐to‐chlorine position, was reported. The catalytic …

Palladium catalysis: dependence of the CC bond synthesis efficiency on carboxylate ligand and alkali metal carboxylate or carboxylic acid additive. Part A: the C (sp 2) …

J Muzart, J Le Bras - Advanced Synthesis and Catalysis, 2023 - hal.science
A variety of Pd-catalyzed reactions are carried out with palladium carboxylates in the
presence of carboxylic acids and/or alkali metal carboxylates. This review is Part A of three …

Acid‐Free Intermolecular Hydroarylation of Acetylene Catalyzed by Dicationic Palladium (II) and Platinum (II) Ethylene Complexes

B Garcia, MM Manjahi, TA Pinion… - European Journal of …, 2024 - Wiley Online Library
Four dicationic palladium and platinum ethylene complexes of the type [M (PNP)(C2H4)] X2
(M= Pd, Pt; X= BF4, SbF6, PNP= 2, 6‐bis (diphenylphosphinomethyl) pyridine) were studied …