Control of intermolecular interactions is integral to harnessing self-assembly in nature. Here
we demonstrate that control of the competition between hydrogen bonds and halogen …

We introduce methyl, methoxy, and phenyl substituents at the para-, meta-, and ortho-
positions of pyridine N-oxide to investigate the effect of chemical substitution on the resulting …

The selective phosphate‐sensing property of a bis‐heteroleptic RuII complex, 1 [PF6] 2,
which has a halogen‐bonding iodotriazole unit, is demonstrated and is shown to be superior …

Halogen bonding (XB) is a highly directional, non-covalent intermolecular interaction
between a molecule (XB donor) presenting a halogen with an electron-deficient region or …

Engaging the nominally terminal oxo atoms of the linear uranyl (UO22+) cation in non‐
covalent interactions represents both a significant challenge and opportunity within the field …

Abstract Mixture of CHCl 3-CH 3 OH is a popular non-aqueous solvent mixture that exhibits
strong synergistic solvation. The specific interaction between the CHCl 3 and CH 3 OH is …

The competition and balance between intermolecular hydrogen bonds (HBs) and halogen
bonds (XBs) were explored by co-crystallizing tetra-functionalized (2× HB (–OH) and 2× XB …

We compare here the halogen bond characteristics of bimolecular adducts involving either
N-bromo-or N-iodosaccharin as strong halogen bond donors, with 4-picoline as a common …

Halogen bonding has been shown to be a versatile interaction for crystal engineering
purposes, with characteristics that parallel those of hydrogen bonding. Here, we explore the …

Through experimental and computational studies we were able to prove that the hydrogen
atom of the imine group forms structurally relevant C–H··· F hydrogen bonds and that the …