Regioselective Synthesis of α-Vinyl Boronates via a Pd-Catalyzed Mizoroki–Heck Reaction

Z Chen, ES Isbrandt, SG Newman - Organic Letters, 2024 - ACS Publications
We report a palladium-catalyzed synthesis of α-vinyl boronates via a regioselective Mizoroki–
Heck reaction between aryl triflates and vinyl boronates. This selectivity is achieved by the …

Pd/Charcoal Catalyzed Reduction of Vinyl Geminal Diboronates

M Lautens, A Torelli - Synfacts, 2023 - thieme-connect.com
Significance: Panda and co-workers report the synthesis of geminal diborylalkanes via a
palladium/charcoal catalyzed reduction of alkenes. Alkyl, aryl, and heteroaryl vinyl geminal …

One pot conversion of phenols and anilines to aldehydes and ketones exploiting α gem boryl carbanions

KK Das, D Aich, S Dey, S Panda - Nature communications, 2024 - nature.com
Functional group interconversion is an important asset in organic synthesis.
Phenols/anilines being naturally abundant and the carbonyl being the most common in a …