Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Recent developments in palladium-catalyzed C–S bond formation

J Li, S Yang, W Wu, H Jiang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Transition metal-catalyzed C–S bond formation reactions have attracted considerable
attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is …

Carboxylate‐Directed C H Functionalization

G Shi, Y Zhang - Advanced Synthesis & Catalysis, 2014 - Wiley Online Library
As a widely existing functional group in organic molecules, the carboxyl group has
numerous advantageous characteristics such as great convenience for further …

Chelation-assisted transition metal-catalysed C–H chalcogenylations

W Ma, N Kaplaneris, X Fang, L Gu, R Mei… - Organic Chemistry …, 2020 - pubs.rsc.org
The development of convenient and mild chalcogenylation reactions for the preparation of
unsymmetrical diaryl sulfides and diaryl selenides has received significant attention in …

Visible Light-Mediated C(sp2)–H Selenylation of Amino Pyrazole and Amino Uracils in the Presence of Rose Bengal as an Organophotocatalyst

D Ali, T Parvin, LH Choudhury - The Journal of Organic Chemistry, 2022 - ACS Publications
Herein, we report an efficient methodology for the synthesis of alkyl, benzyl, and phenyl
selenoethers of aminopyrazoles and aminouracils by C (sp2)–H functionalization in the …

Ruthenium (II)-catalyzed hydroarylation of maleimides using carboxylic acids as a traceless directing group

A Mandal, H Sahoo, S Dana, M Baidya - Organic letters, 2017 - ACS Publications
An efficient Ru (II)-catalyzed hydroarylation of maleimides with ready-stock aryl carboxylic
acids has been developed based on weak carboxylate-directed ortho-C–H alkylation and …

Metal-free regioselective C–H chalcogenylation of coumarins/(hetero) arenes at ambient temperature

Z Song, C Ding, S Wang, Q Dai, Y Sheng… - Chemical …, 2020 - pubs.rsc.org
A novel, practical and metal-free approach for the regioselective selenation of coumarins
employing (bis (trifluoroacetoxy) iodo) benzene (PIFA) at room temperature is presented …

Diorganyl diselenides: a powerful tool for the construction of selenium containing scaffolds

AD Sonawane, RA Sonawane, M Ninomiya… - Dalton …, 2021 - pubs.rsc.org
Organoselenium compounds find versatile applications in organic synthesis, materials
synthesis, and ligand chemistry. Organoselenium heterocycles are widely studied agents …

Electrochemical Synthesis of Thienoacene Derivatives: Transition‐Metal‐Free Dehydrogenative C− S Coupling Promoted by a Halogen Mediator

K Mitsudo, R Matsuo, T Yonezawa… - Angewandte Chemie …, 2020 - Wiley Online Library
The first electrochemical dehydrogenative C− S bond formation leading to thienoacene
derivatives is described. Several thienoacene derivatives were synthesized by …