Poly (lactic acid)-based biomaterials: synthesis, modification and applications

L **ao, B Wang, G Yang… - … science, engineering and …, 2012 - books.google.com
Social and economic development has driven considerable scientific and engineering
efforts on the discovery, development, and utilization of polymers. Widespread reliance in …

Catalytic Systems for the Production of Poly (lactic acid)

JA Byers, AB Biernesser, KR Delle Chiaie… - Synthesis, Structure and …, 2018 - Springer
Different ways of synthesizing poly (lactic acid) are reviewed. Emphasis is placed on the
development of various catalysts for the ring-opening polymerization of lactide, which has …

Recent Developments in Metal-Catalyzed Ring-Opening Polymerization of Lactides and Glycolides: Preparation of Polylactides, Polyglycolide, and Poly(lactide-co …

S Dutta, WC Hung, BH Huang, CC Lin - Synthetic Biodegradable Polymers, 2011 - Springer
A good synergy of a catalytic system's components, such as ancillary ligands and leaving
groups at the active site of a catalyst, is of fundamental importance in the ring-opening …

Toughened PLA-b-PCL-b-PLA triblock copolymer based biomaterials: Effect of self-assembled nanostructure and stereocomplexation on the mechanical properties

N Mulchandani, K Masutani, S Kumar, H Yamane… - Polymer …, 2021 - pubs.rsc.org
The current research unfolds the effect of block lengths, microdomain morphology and
stereocomplexation on the mechanical properties of PLA-b-PCL-b-PLA triblock copolymers …

A novel cationic copper (II) Schiff base complex: Synthesis, characterization, crystal structure, electrochemical evaluation, anti-cancer activity, and preparation of its …

SY Ebrahimipour, I Sheikhshoaie, J Castro… - Inorganica Chimica …, 2015 - Elsevier
Abstract A tridentate ONO ligand (E)-N′-((2-hydroxynaphthalen-1-yl) methylene)
acetohydrazide [HL] and its cationic Cu (II) complex [Cu (L)(H 2 O)] NO 3 were synthesized …

The use of Cu and Zn salicylaldimine complexes as catalyst precursors in ring opening polymerization of lactides: ligand effects on polymer characteristics

S Bhunora, J Mugo, A Bhaw‐Luximon… - Applied …, 2011 - Wiley Online Library
A range of monomeric tetra‐coordinate copper (II) and zinc (II) complexes based on N, O‐
bidentate salicylaldimine Schiff base ligands has been synthesized and characterized using …

Bis (3, 5-dimethylpyrazole) copper (II) and zinc (II) complexes as efficient initiators for the ring opening polymerization of ε-caprolactone and d, l-lactide

D Appavoo, B Omondi, IA Guzei, JL Van Wyk… - Polyhedron, 2014 - Elsevier
Dimethylpyrazole (L), reacts with [Cu (OAc) 2] or [Zn (OAc) 2]; and either C 6 H 5 COOH, 4-
OH–C 6 H 5 COOH, 3, 5-NO 2–C 6 H 5 COOH or 2-Cl–C 6 H 5 COOH to afford the …

Square-planar Cu (II) diketiminate complexes in lactide polymerization

TJJ Whitehorne, F Schaper - Inorganic Chemistry, 2013 - ACS Publications
Cu (O i Pr) 2 was reacted with several β-diketimine ligands, nacnac RH. Sterically
undemanding ligands with N-benzyl substituents afforded the dimeric heteroleptic …

In Situ Imine-Based Linker Formation for the Synthesis of Zirconium MOFs: A Route to CO2 Capture Materials and Ethylene Oligomerization Catalysts

USF Arrozi, V Bon, S Krause, T Lübken… - Inorganic …, 2019 - ACS Publications
In situ formation of imine-based organic linkers facilitates the formation of metal–organic
frameworks (MOFs), in particular if linker solubility hampers the direct synthesis. The …

Bulk solvent-free melt ring-opening polymerization (ROP) of L-lactide catalyzed by Ni (II) and Ni (II)–Ln (III) complexes based on the acyclic Salen-type Schiff-base …

L Ding, W **, Z Chu, L Chen, X Lü, G Yuan… - Inorganic Chemistry …, 2011 - Elsevier
Abstract A monometallic (Ni 2+, 1) and a series of heterometallic (Ni 2+–Ln 3+, Ln= Ce (2);
Ln= Nd (3); Ln= Sm (4); Ln= Eu (5); Ln= Tb (6); Ln= Ho (7); Ln= Tm (8)) complexes based on …