Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …

The Suzuki-Miyaura reaction (SMR), involving the coupling of an organoboron reagent and
an organic halide or pseudo-halide in the presence of a palladium or nickel catalyst and a …

The synthesis of biaryl compounds by the transition-metal free coupling of arenes is an
important contemporary challenge, aiming to avoid the toxicity and cost profiles associated …

Two new classes of highly active yet air-and moisture-stable π-R-allylpalladium complexes
containing bulky biaryl-and bipyrazolylphosphines with extremely broad ligand scope have …

In the development of transition metal catalysis, the process of ligand screening, where an
optimal ligand for a reaction of interest is identified from a large variety of candidate …

The synthesis of biphenyls under mild conditions is really a challenge to green chemistry.
Here we report a facile photodeposition strategy to fabricate a Pd/gC 3 N 4 nanocomposite …

We report the Pd-catalyzed arylation of very hindered α, α, α-trisubstituted primary amines.
Kinetics-based mechanistic analysis and rational design have led to the development of two …

A series of oxidative addition complexes with a general formula (t Bu3P) Pd (Ar) X, as a
class of precatalysts, were synthesized for challenging Suzuki–Miyaura coupling involving …

This review surveys recent developments (reported in the last fifteen years) in
organometallic‐chemistry‐based methods for the functionalization of imidazo [1, 2‐a] …