A fruitful decade of organofluorine chemistry: new reagents and reactions

FL Qing, XY Liu, JA Ma, Q Shen, Q Song… - CCS …, 2022 - chinesechemsoc.org
The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

Radical trifluoromethylation

H **ao, Z Zhang, Y Fang, L Zhu, C Li - Chemical Society Reviews, 2021 - pubs.rsc.org
Radical trifluoromethylation - Chemical Society Reviews (RSC Publishing) DOI:10.1039/D1CS00200G
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article Check for updates …

Contemporary synthetic strategies in organofluorine chemistry

R Britton, V Gouverneur, JH Lin, M Meanwell… - Nature Reviews …, 2021 - nature.com
Fluorinated molecules have a wide range of applications and are used as medicines,
agrochemicals and refrigerants and in smartphone liquid crystal displays, photovoltaic solar …

Late-stage difluoromethylation: concepts, developments and perspective

JBI Sap, CF Meyer, NJW Straathof… - Chemical Society …, 2021 - pubs.rsc.org
This review describes the recent advances made in difluoromethylation processes based on
X–CF2H bond formation where X is C (sp), C (sp2), C (sp3), O, N or S, a field of research …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Copper–Carbon Homolysis Competes with Reductive Elimination in Well-Defined Copper (III) Complexes

W Yan, S Carter, CT Hsieh, JA Krause… - Journal of the …, 2023 - ACS Publications
Despite the recent advancements of Cu catalysis for the cross-coupling of alkyl electrophiles
and the frequently proposed involvement of alkyl–Cu (III) complexes in such reactions, little …

Electrifying green synthesis: recent advances in electrochemical annulation reactions

GM Martins, GC Zimmer, SR Mendes, N Ahmed - Green Chemistry, 2020 - pubs.rsc.org
Electricity originating from renewable resources can be used for highly sustainable and
economically attractive applications. With electrons as the mass-free reagent, the use of a …

Direct C–H difluoromethylation of heterocycles via organic photoredox catalysis

W Zhang, XX **ang, J Chen, C Yang, YL Pan… - Nature …, 2020 - nature.com
The discovery of modern medicine relies on the sustainable development of synthetic
methodologies to meet the needs associated with drug molecular design. Heterocycles …

Wonderful fusion of organofluorine chemistry and decarboxylation strategy

P **ao, X Pannecoucke, JP Bouillon… - Chemical Society …, 2021 - pubs.rsc.org
Decarboxylation strategy has been emerging as a powerful tool for the synthesis of fluorine-
containing organic compounds that play important roles in various fields such as …

Iron-mediated ligand-to-metal charge transfer enables 1, 2-diazidation of alkenes

M Zhang, J Zhang, Q Li, Y Shi - Nature Communications, 2022 - nature.com
Given the widespread significance of vicinal diamine units in organic synthesis,
pharmaceuticals and functional materials, as well as in privileged molecular catalysts, an …