Linear, graft, and beyond: multiblock copolymers as next-generation compatibilizers
Properly addressing the global issue of unsustainable plastic waste generation and
accumulation will require a confluence of technological breakthroughs on various fronts …
accumulation will require a confluence of technological breakthroughs on various fronts …
Sequence and entropy-based control of complex coacervates
Biomacromolecules rely on the precise placement of monomers to encode information for
structure, function, and physiology. Efforts to emulate this complexity via the synthetic control …
structure, function, and physiology. Efforts to emulate this complexity via the synthetic control …
[HTML][HTML] Model for disordered proteins with strongly sequence-dependent liquid phase behavior
Phase separation of intrinsically disordered proteins is important for the formation of
membraneless organelles or biomolecular condensates, which play key roles in the …
membraneless organelles or biomolecular condensates, which play key roles in the …
Gradient copolymers–Preparation, properties and practice
Gradient copolymers are members of a unique class of copolymer in which the monomer
composition changes gradually from one end of the polymer chain to the other. In general …
composition changes gradually from one end of the polymer chain to the other. In general …
100th anniversary of macromolecular science viewpoint: Opportunities in the physics of sequence-defined polymers
Polymer science has been driven by ever-increasing molecular complexity, as polymer
synthesis expands an already-vast palette of chemical and architectural parameter space …
synthesis expands an already-vast palette of chemical and architectural parameter space …
Designing electrostatic interactions via polyelectrolyte monomer sequence
Charged polymers are ubiquitous in biological systems because electrostatic interactions
can drive complicated structure formation and respond to environmental parameters such as …
can drive complicated structure formation and respond to environmental parameters such as …
Unsupervised learning of sequence-specific aggregation behavior for a model copolymer
We apply a recently developed unsupervised machine learning scheme for local
environments [Reinhart, Comput. Mater. Sci., 2021, 196, 110511] to characterize large …
environments [Reinhart, Comput. Mater. Sci., 2021, 196, 110511] to characterize large …
[HTML][HTML] Micro-to macro-phase separation transition in sequence-defined coacervates
CE Sing - The Journal of Chemical Physics, 2020 - pubs.aip.org
Phase separation can be driven by the association of oppositely charged polyelectrolytes in
solution, a process known as complex coacervation. This can manifest as macrophase …
solution, a process known as complex coacervation. This can manifest as macrophase …
Role of solvation on diffusion of ions in diblock copolymers: understanding the molecular weight effect through modeling
Salt-doped diblock copolymers with microphase-separated domains of both an ion
conductive and a mechanically strong polymer have been extensively studied due to their …
conductive and a mechanically strong polymer have been extensively studied due to their …
Machine Learning Models and Dimensionality Reduction for Prediction of Polymer Properties
Accurate prediction of block polymer properties as a function of monomer sequence is
necessary for better material development. The number of permutations of chemistry and …
necessary for better material development. The number of permutations of chemistry and …