Linear, graft, and beyond: multiblock copolymers as next-generation compatibilizers

JL Self, AJ Zervoudakis, X Peng, WR Lenart… - JACs Au, 2022 - ACS Publications
Properly addressing the global issue of unsustainable plastic waste generation and
accumulation will require a confluence of technological breakthroughs on various fronts …

Sequence and entropy-based control of complex coacervates

LW Chang, TK Lytle, M Radhakrishna… - Nature …, 2017 - nature.com
Biomacromolecules rely on the precise placement of monomers to encode information for
structure, function, and physiology. Efforts to emulate this complexity via the synthetic control …

[HTML][HTML] Model for disordered proteins with strongly sequence-dependent liquid phase behavior

A Statt, H Casademunt, CP Brangwynne… - The Journal of …, 2020 - pubs.aip.org
Phase separation of intrinsically disordered proteins is important for the formation of
membraneless organelles or biomolecular condensates, which play key roles in the …

Gradient copolymers–Preparation, properties and practice

MM Alam, KS Jack, DJT Hill, AK Whittaker… - European Polymer …, 2019 - Elsevier
Gradient copolymers are members of a unique class of copolymer in which the monomer
composition changes gradually from one end of the polymer chain to the other. In general …

100th anniversary of macromolecular science viewpoint: Opportunities in the physics of sequence-defined polymers

SL Perry, CE Sing - ACS Macro Letters, 2020 - ACS Publications
Polymer science has been driven by ever-increasing molecular complexity, as polymer
synthesis expands an already-vast palette of chemical and architectural parameter space …

Designing electrostatic interactions via polyelectrolyte monomer sequence

TK Lytle, LW Chang, N Markiewicz, SL Perry… - ACS central …, 2019 - ACS Publications
Charged polymers are ubiquitous in biological systems because electrostatic interactions
can drive complicated structure formation and respond to environmental parameters such as …

Unsupervised learning of sequence-specific aggregation behavior for a model copolymer

A Statt, DC Kleeblatt, WF Reinhart - Soft matter, 2021 - pubs.rsc.org
We apply a recently developed unsupervised machine learning scheme for local
environments [Reinhart, Comput. Mater. Sci., 2021, 196, 110511] to characterize large …

[HTML][HTML] Micro-to macro-phase separation transition in sequence-defined coacervates

CE Sing - The Journal of Chemical Physics, 2020 - pubs.aip.org
Phase separation can be driven by the association of oppositely charged polyelectrolytes in
solution, a process known as complex coacervation. This can manifest as macrophase …

Role of solvation on diffusion of ions in diblock copolymers: understanding the molecular weight effect through modeling

Y Seo, KH Shen, JR Brown, LM Hall - Journal of the American …, 2019 - ACS Publications
Salt-doped diblock copolymers with microphase-separated domains of both an ion
conductive and a mechanically strong polymer have been extensively studied due to their …

Machine Learning Models and Dimensionality Reduction for Prediction of Polymer Properties

JA Mysona, PF Nealey, JJ de Pablo - Macromolecules, 2024 - ACS Publications
Accurate prediction of block polymer properties as a function of monomer sequence is
necessary for better material development. The number of permutations of chemistry and …