Review of 4D printing materials and their properties

DG Shin, TH Kim, DE Kim - International Journal of Precision Engineering …, 2017 - Springer
Since its introduction, the 3D printing technology has been widely used in fields such as
design, rapid prototy**, and biomedical devices, owing to its advantages of inexpensive …

PhotoROMP: The Future Is Bright

AJ Greenlee, RA Weitekamp, JC Foster… - ACS …, 2024 - ACS Publications
Since the earliest investigations of olefin metathesis catalysis, light has been the choice for
controlling the catalyst activity on demand. From the perspective of energy efficiency …

Plasmonic visible–near infrared photothermal activation of olefin metathesis enabling photoresponsive materials

N Lemcoff, NB Nechmad, O Eivgi, E Yehezkel… - Nature Chemistry, 2023 - nature.com
Light-induced catalysis and thermoplasmonics are promising fields creating many
opportunities for innovative research. Recent advances in light-induced olefin metathesis …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Visible-light-controlled ruthenium-catalyzed olefin metathesis

C Theunissen, MA Ashley, T Rovis - Journal of the American …, 2019 - ACS Publications
Olefin metathesis is now one of the most efficient ways to create new carbon–carbon bonds.
While most efforts focused on the development of ever-more efficient catalysts, a particular …

Photoinitiated olefin metathesis and stereolithographic printing of polydicyclopentadiene

SC Leguizamon, NT Monk, MT Hochrein… - …, 2022 - ACS Publications
Recent progress in photoinitiated ring-opening metathesis polymerization (photoROMP) has
enabled the lithographic production of patterned films from olefinic resins. Recently, we …

Light-activated olefin metathesis: catalyst development, synthesis, and applications

O Eivgi, RS Phatake, NB Nechmad… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The most important means for tuning and improving a catalyst's properties is the
delicate exchange of the ligand shell around the central metal atom. Perhaps for no other …

Mediating reaction orthogonality in polymer and materials science

N Corrigan, M Ciftci, K Jung… - Angewandte Chemie …, 2021 - Wiley Online Library
Selective control of chemical reactions is critical for the proper regulation of processes
ranging from intricate biological systems to large scale industrial manufacturing. The …

Photoinduced ring-opening polymerizations

N Guy, O Giani, S Blanquer, J Pinaud… - Progress in Organic …, 2021 - Elsevier
Photopolymerization is the subject of a growing interest both at industrial and academic
levels because it provides high reaction kinetics, low emissions of volatile organic solvents …

Ruthenium Olefin Metathesis Catalysts with Six-Membered Chelating Dithioacetal Ligands: Synthesis and Reactivity

G Segalovich-Gerendash, M Baranov… - …, 2023 - ACS Publications
Ruthenium sulfur-chelated benzylidenes possessing five-membered chelating architectures
exhibiting latency and excellent thermal and photochemical activation behavior in various …