Spectroelectrochemistry: the best of two worlds

W Kaim, J Fiedler - Chemical Society Reviews, 2009 - pubs.rsc.org
The combination of reaction-oriented electrochemistry with species-focussed spectroscopy
in spectroelectrochemistry (SEC) allows for a more complete analysis of single and multiple …

Recent advances in triphenylamine-based electrochromic derivatives and polymers

HJ Yen, GS Liou - Polymer Chemistry, 2018 - pubs.rsc.org
Triphenylamine-containing electrochromic materials revealing significant color changes by
electrochemically induced redox reactions are attractive with great potential for low energy …

Manifestations of noninnocent ligand behavior

W Kaim - Inorganic Chemistry, 2011 - ACS Publications
The potential of redox-active ligands to behave “noninnocently” in transition-metal
coordination compounds is reflected with respect to various aspects and situations. These …

Metal-coordinated azoaromatics: Strategies for sequential azo-reduction, isomerization and application potential

S Panda, S Dhara, A Singh, S Dey, GK Lahiri - Coordination Chemistry …, 2023 - Elsevier
Reversible electron reservoir feature of redox non-innocent ligand is an important event from
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …

Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

Electronic communication through unsaturated hydrocarbon bridges in homobimetallic organometallic complexes

P Aguirre-Etcheverry, D O'Hare - Chemical reviews, 2010 - ACS Publications
Bimetallic (binuclear metal) complexes contain two metal centers, either linked directly or, as
in the complexes considered in this review, through a bridging ligand. Homometallic …

Anticancer properties, apoptosis and catecholase mimic activities of dinuclear cobalt (II) and copper (II) Schiff base complexes

MN Ahamad, K Iman, MK Raza, M Kumar, A Ansari… - Bioorganic …, 2020 - Elsevier
The present work describes coordination chemistry and biological evaluation of two novel
dinuclear complexes [Co 2 (HL 1) 2 (H 2 O) 2]· 8H 2 O (1) and [Cu 2 (L 2) 2](2) obtained from …

Concepts for metal complex chromophores absorbing in the near infrared

W Kaim - Coordination Chemistry Reviews, 2011 - Elsevier
The near-infrared (750–2500nm) region of the electromagnetic spectrum has received
enhanced attention recently from the areas of atmospheric and analytical chemistry, from …

Heteromultimetallic Complexes with Redox‐Active Mesoionic Carbenes: Control of Donor Properties and Redox‐Induced Catalysis

L Hettmanczyk, L Suntrup, S Klenk… - … A European Journal, 2017 - Wiley Online Library
Mesoionic carbenes (MICs) are currently hugely popular as ligands, and triazolylidenes are
arguably the most prominent classes of such MICs. Mesoionic carbenes with ferrocenyl …

Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties

K Costuas, S Rigaut - Dalton Transactions, 2011 - pubs.rsc.org
In this Perspective, we highlight the non-innocent behaviour of the bridging ligand in
organometallic polynuclear metallic complexes displaying metal-carbon σ bonds between …