Fluorinated metal–organic frameworks for gas separation

AE Amooghin, H Sanaeepur, R Luque… - Chemical Society …, 2022 - pubs.rsc.org
Fluorinated metal–organic frameworks (F-MOFs) as fast-growing porous materials have
revolutionized the field of gas separation due to their tunable pore apertures, appealing …

Progress and potential of metal-organic frameworks (MOFs) for gas storage and separation: A review

T Jia, Y Gu, F Li - Journal of Environmental Chemical Engineering, 2022 - Elsevier
Gas storage and separation plays the most critically vital role in the utilization of energy
resources and the petrochemical industry in modern society. The development of industry …

Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation

J Wang, Y Zhang, Y Su, X Liu, P Zhang, RB Lin… - Nature …, 2022 - nature.com
The separation of C2H2/CO2 is not only industrially important for acetylene purification but
also scientifically challenging owing to their high similarities in physical properties and …

Isoreticular chemistry within metal–organic frameworks for gas storage and separation

W Fan, X Zhang, Z Kang, X Liu, D Sun - Coordination chemistry reviews, 2021 - Elsevier
Precise control of the pore size and environment of metal–organic framework (MOF) is a
necessary condition for achieving high performance of gas adsorption and separation. After …

Topological design of unprecedented metal‐organic frameworks featuring multiple anion functionalities and hierarchical porosity for benchmark acetylene separation

Y Zhang, W Sun, B Luan, J Li, D Luo… - Angewandte Chemie …, 2023 - Wiley Online Library
Separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4) is industrially
important but still challenging so far. Herein, we developed two novel robust metal organic …

Postsynthetic modification: an enabling technology for the advancement of metal–organic frameworks

M Kalaj, SM Cohen - ACS Central Science, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of porous materials with immense chemical
tunability derived from their organic and inorganic building blocks. Presynthetic approaches …

Immobilization of the polar group into an ultramicroporous metal–organic framework enabling benchmark inverse selective CO2/C2H2 separation with record C2H2 …

SQ Yang, R Krishna, H Chen, L Li, L Zhou… - Journal of the …, 2023 - ACS Publications
One-step harvest of high-purity light hydrocarbons without the desorption process
represents an advanced and highly efficient strategy for the purification of target substances …

Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

OT Qazvini, R Babarao, SG Telfer - Nature communications, 2021 - nature.com
Efficient and sustainable methods for carbon dioxide capture are highly sought after. Mature
technologies involve chemical reactions that absorb CO2, but they have many drawbacks …

Dense Packing of Acetylene in a Stable and Low‐Cost Metal–Organic Framework for Efficient C2H2/CO2 Separation

J Pei, HM Wen, XW Gu, QL Qian, Y Yang… - Angewandte Chemie …, 2021 - Wiley Online Library
Porous materials for C2H2/CO2 separation mostly suffer from high regeneration energy,
poor stability, or high cost that largely dampen their industrial implementation. A desired …

Benchmark C2H2/CO2 Separation in an Ultra‐Microporous Metal–Organic Framework via Copper(I)‐Alkynyl Chemistry

L Zhang, K Jiang, L Yang, L Li, E Hu… - Angewandte …, 2021 - Wiley Online Library
Separation of acetylene from carbon dioxide remains a daunting challenge because of their
very similar molecular sizes and physical properties. We herein report the first example of …