Mercury physicochemical and biogeochemical transformation in the atmosphere and at atmospheric interfaces: A review and future directions

PA Ariya, M Amyot, A Dastoor, D Deeds… - Chemical …, 2015 - ACS Publications
Mercury is a fascinating fluid metal that exists as liquid at 25 C (0 C= 273 K). This silver
colored d-block heavy metal exhibits noble-gas-like characteristics and solidifies at a …

Global biogeochemical cycling of mercury: a review

NE Selin - Annual review of environment and resources, 2009 - annualreviews.org
Mercury pollution poses global human health and environmental risks. Although mercury is
naturally present in the environment, human activities, such as coal burning, have increased …

A new mechanism for atmospheric mercury redox chemistry: implications for the global mercury budget

HM Horowitz, DJ Jacob, Y Zhang… - Atmospheric …, 2017 - acp.copernicus.org
Mercury (Hg) is emitted to the atmosphere mainly as volatile elemental Hg 0. Oxidation to
water-soluble Hg II plays a major role in Hg deposition to ecosystems. Here, we implement a …

A synthesis of progress and uncertainties in attributing the sources of mercury in deposition

S Lindberg, R Bullock, R Ebinghaus… - AMBIO: a Journal of the …, 2007 - BioOne
A panel of international experts was convened in Madison, Wisconsin, in 2005, as part of the
8th International Conference on Mercury as a Global Pollutant. Our charge was to address …

Global atmospheric model for mercury including oxidation by bromine atoms

CD Holmes, DJ Jacob, ES Corbitt, J Mao… - Atmospheric …, 2010 - acp.copernicus.org
Global models of atmospheric mercury generally assume that gas-phase OH and ozone are
the main oxidants converting Hg 0 to Hg II and thus driving mercury deposition to …

The chemistry of atmospheric mercury: a review

CJ Lin, SO Pehkonen - Atmospheric environment, 1999 - Elsevier
The atmosphere is an important transient reservoir of mercury. In addition to its great
capacity, the chemical processes transforming mercury between the elemental and divalent …

Photoreduction of gaseous oxidized mercury changes global atmospheric mercury speciation, transport and deposition

A Saiz-Lopez, SP Sitkiewicz, D Roca-Sanjuán… - Nature …, 2018 - nature.com
Abstract Anthropogenic mercury (Hg (0)) emissions oxidize to gaseous Hg (II) compounds,
before deposition to Earth surface ecosystems. Atmospheric reduction of Hg (II) competes …

Chemical cycling and deposition of atmospheric mercury: Global constraints from observations

NE Selin, DJ Jacob, RJ Park… - Journal of …, 2007 - Wiley Online Library
We use a global 3‐D model of atmospheric mercury (GEOS‐Chem) to interpret worldwide
observations of total gaseous mercury (TGM) and reactive gaseous mercury (RGM) in terms …

Mercury isotope fractionation during photoreduction in natural water is controlled by its Hg/DOC ratio

W Zheng, H Hintelmann - Geochimica et Cosmochimica Acta, 2009 - Elsevier
Photoreduction of Hg in natural water plays a crucial role in the production of elemental Hg
and its biogeochemical cycle. Solar irradiation and dissolved organic carbon (DOC) in water …

Removal of aqueous Cr (VI) by a combination of photocatalytic reduction and coprecipitation

X Wang, SO Pehkonen, AK Ray - Industrial & Engineering …, 2004 - ACS Publications
Semiconductor photocatalytic reduction is a relatively new technique for the removal of
dissolved toxic metal ions from wastewater. In this paper, adsorption and photocatalytic …