Observing and understanding the phenomena associated with the reaction mechanisms
and catalyst deactivation in molecular catalysis is a very challenging task in green chemistry …

Metal/lipase-combo catalyzed dynamic kinetic resolution (DKR) of racemic chiral alcohols is
a general and practical process to obtain the corresponding enantiopure esters R with …

Chemoselective reductive conversion of organic and inorganic compounds has been
developed by the combination of samarium (II) diiodide (SmI2) and water. Despite the …

Main observation and conclusion Pd (OAc) 2 is an extensively utilized palladium source in
the palladium initiated transformations either directly or as a catalyst precursor. However, the …

The reductive cross-electrophile coupling, enabling direct binding of carbon electrophiles,
has many benefits over conventional cross-coupling methods that require a carbon …

Microreactor chemistry has evolved over the past two decades, showing great promise in the
chemical industry, pharmaceuticals, fine chemicals, and in chemical synthesis research …

The catalytic alkylation of amines with alcohols is a highly atom-economical approach that
produces water as the sole by-product. Existing catalytic systems lack generality and are …

Dynamic kinetic resolution allows for the synthesis of enantiomerically pure asymmetric
alcohols. Cyclopentadienyl-derived ruthenium catalysts were immobilized with an ionic …

NiII cyclam (cyclam= 1, 4, 8, 11-tetraazacyclotetradecane) is an efficient catalyst for the
selective reduction of CO2 to CO. A crucial elementary step in the proposed catalytic cycle is …

Metalcyclopentadienyl complexes (MCp)+(M= Fe, Ru, Os) bound to the large polyaromatic
hydrogenated hydrocarbon (PAH) C96H24 used as a model for pristine graphene have …