Gold (I)-catalyzed activation of alkynes for the construction of molecular complexity
For centuries, gold had been considered a precious, purely decorative inert metal. It was not
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …
Gold-catalyzed carbon− heteroatom bond-forming reactions
After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …
this noble metal have been increasingly emerging in the literature over the past 2 decades …
Gold-catalyzed conversion of highly strained compounds
The past decade has witnessed the golden age of homogeneous gold-catalyzed reactions,
especially those that involve the transformation of highly strained molecules into complex …
especially those that involve the transformation of highly strained molecules into complex …
Strained small rings in gold-catalyzed rapid chemical transformations
BL Lu, L Dai, M Shi - Chemical Society Reviews, 2012 - pubs.rsc.org
Gold-catalyzed reactions, which have been widely explored over the past several years, are
powerful tools in organic synthesis to access complex molecular frameworks, and some …
powerful tools in organic synthesis to access complex molecular frameworks, and some …
[HTML][HTML] Mechanistic surprises in the gold (I)-catalyzed intramolecular hydroarylation of allenes
D Weber, MA Tarselli, MR Gagné - … Chemie (International ed. in …, 2009 - ncbi.nlm.nih.gov
Gold (I)-catalyzed carbon-carbon bond forming reactions continue to fascinate the synthetic
community but are less well investigated than many conventional metal catalysts.[1] In many …
community but are less well investigated than many conventional metal catalysts.[1] In many …
Performance of density functional theory on homogeneous gold catalysis
ON Faza, RÁ Rodríguez, CS López - Theoretical Chemistry Accounts, 2011 - Springer
The performance of 32 density functionals to describe the homogeneous gold catalysis of
propargyl esters has been tested. These catalytic reactions are very commonly rather …
propargyl esters has been tested. These catalytic reactions are very commonly rather …
Cu (I)-catalyzed oxidative cyclization of alkynyl oxiranes and oxetanes
C Gronnier, S Kramer, Y Odabachian… - Journal of the American …, 2012 - ACS Publications
In the presence of a Cu (I) catalyst and a pyridine oxide, alkynyl oxiranes and oxetanes can
be converted into functionalized five-or six-membered α, β-unsaturated lactones or …
be converted into functionalized five-or six-membered α, β-unsaturated lactones or …
Enhancement of foam stability parallel with foamability of the foam stabilized by sodium caseinate-based complex: Octenyl succinate starch acting a dual role
Interaction among the multiple components play a crucial role in regulating the foam
properties. In this work, the relationship among the interaction of sodium caseinate …
properties. In this work, the relationship among the interaction of sodium caseinate …
Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via huisgen cycloaddition studies
A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles
directly from oximes and alkynes was developed via independent optimization of two key …
directly from oximes and alkynes was developed via independent optimization of two key …
Mechanism study of the gold-catalyzed cycloisomerization of α-aminoallenes: oxidation state of active species and influence of counterion
RX Zhu, DJ Zhang, JX Guo, JL Mu… - The Journal of …, 2010 - ACS Publications
A computational study with the B3LYP density functional theory was carried out to study the
reaction mechanism for the cycloisomerization of allenes catalyzed by Au (I) and Au (III) …
reaction mechanism for the cycloisomerization of allenes catalyzed by Au (I) and Au (III) …