Towards single-species selectivity of membranes with subnanometre pores
Synthetic membranes with pores at the subnanometre scale are at the core of processes for
separating solutes from water, such as water purification and desalination. While these …
separating solutes from water, such as water purification and desalination. While these …
Ion–ion selectivity of synthetic membranes with confined nanostructures
Synthetic membranes featuring confined nanostructures have emerged as a prominent
category of leading materials that can selectively separate target ions from complex water …
category of leading materials that can selectively separate target ions from complex water …
Solar transpiration–powered lithium extraction and storage
Lithium mining is energy intensive and environmentally costly. This is because lithium ions
are typically present in brines as a minor component mixed with physiochemically similar …
are typically present in brines as a minor component mixed with physiochemically similar …
Intrapore energy barriers govern ion transport and selectivity of desalination membranes
State-of-the-art desalination membranes exhibit high water-salt selectivity, but their ability to
discriminate between ions is limited. Elucidating the fundamental mechanisms underlying …
discriminate between ions is limited. Elucidating the fundamental mechanisms underlying …
Critical knowledge gaps in mass transport through single-digit nanopores: A review and perspective
Not all nanopores are created equal. By definition, nanopores have characteristic diameters
or conduit widths between∼ 1 and 100 nm. However, the narrowest of such pores, perhaps …
or conduit widths between∼ 1 and 100 nm. However, the narrowest of such pores, perhaps …
Comparison of energy consumption in desalination by capacitive deionization and reverse osmosis
Capacitive deionization (CDI), which is based on the electrosorption of ions by porous
electrodes, is an emerging technology for brackish water desalination. Understanding the …
electrodes, is an emerging technology for brackish water desalination. Understanding the …
Selective removal of divalent cations by polyelectrolyte multilayer nanofiltration membrane: Role of polyelectrolyte charge, ion size, and ionic strength
We fabricated polyelectrolyte multilayer (PEM) nanofiltration (NF) membranes using a layer-
by-layer (LbL) method for effective removal of scale-forming divalent cations (Mg 2+, Ca 2+ …
by-layer (LbL) method for effective removal of scale-forming divalent cations (Mg 2+, Ca 2+ …
Role of ionic charge density in donnan exclusion of monovalent anions by nanofiltration
The main objective of this study is to examine how the charge densities of four monovalent
anions—fluoride (F–), chloride (Cl–), bromide (Br–), and nitrate (NO3–)—influence their …
anions—fluoride (F–), chloride (Cl–), bromide (Br–), and nitrate (NO3–)—influence their …
Activation behavior for ion permeation in ion-exchange membranes: Role of ion dehydration in selective transport
We explored the mechanisms governing the selectivity of anion-and cation-exchange
membranes for the transport of four monovalent anions (ie, fluoride, chloride, bromide, and …
membranes for the transport of four monovalent anions (ie, fluoride, chloride, bromide, and …
Comparison of ion selectivity in electrodialysis and capacitive deionization
Ion-selective removal is an important frontier in water purification technologies. For many
emerging applications, removing all ions indiscriminately can lead to excessive energy …
emerging applications, removing all ions indiscriminately can lead to excessive energy …