Towards single-species selectivity of membranes with subnanometre pores

R Epsztein, RM DuChanois, CL Ritt, A Noy… - Nature …, 2020 - nature.com
Synthetic membranes with pores at the subnanometre scale are at the core of processes for
separating solutes from water, such as water purification and desalination. While these …

Ion–ion selectivity of synthetic membranes with confined nanostructures

K Liu, R Epsztein, S Lin, J Qu, M Sun - ACS nano, 2024 - ACS Publications
Synthetic membranes featuring confined nanostructures have emerged as a prominent
category of leading materials that can selectively separate target ions from complex water …

Solar transpiration–powered lithium extraction and storage

Y Song, S Fang, N Xu, M Wang, S Chen, J Chen, B Mi… - Science, 2024 - science.org
Lithium mining is energy intensive and environmentally costly. This is because lithium ions
are typically present in brines as a minor component mixed with physiochemically similar …

Intrapore energy barriers govern ion transport and selectivity of desalination membranes

X Zhou, Z Wang, R Epsztein, C Zhan, W Li… - Science …, 2020 - science.org
State-of-the-art desalination membranes exhibit high water-salt selectivity, but their ability to
discriminate between ions is limited. Elucidating the fundamental mechanisms underlying …

Critical knowledge gaps in mass transport through single-digit nanopores: A review and perspective

S Faucher, N Aluru, MZ Bazant… - The Journal of …, 2019 - ACS Publications
Not all nanopores are created equal. By definition, nanopores have characteristic diameters
or conduit widths between∼ 1 and 100 nm. However, the narrowest of such pores, perhaps …

Comparison of energy consumption in desalination by capacitive deionization and reverse osmosis

M Qin, A Deshmukh, R Epsztein, SK Patel… - Desalination, 2019 - Elsevier
Capacitive deionization (CDI), which is based on the electrosorption of ions by porous
electrodes, is an emerging technology for brackish water desalination. Understanding the …

Selective removal of divalent cations by polyelectrolyte multilayer nanofiltration membrane: Role of polyelectrolyte charge, ion size, and ionic strength

W Cheng, C Liu, T Tong, R Epsztein, M Sun… - Journal of membrane …, 2018 - Elsevier
We fabricated polyelectrolyte multilayer (PEM) nanofiltration (NF) membranes using a layer-
by-layer (LbL) method for effective removal of scale-forming divalent cations (Mg 2+, Ca 2+ …

Role of ionic charge density in donnan exclusion of monovalent anions by nanofiltration

R Epsztein, E Shaulsky, N Dizge… - … science & technology, 2018 - ACS Publications
The main objective of this study is to examine how the charge densities of four monovalent
anions—fluoride (F–), chloride (Cl–), bromide (Br–), and nitrate (NO3–)—influence their …

Activation behavior for ion permeation in ion-exchange membranes: Role of ion dehydration in selective transport

R Epsztein, E Shaulsky, M Qin, M Elimelech - Journal of membrane …, 2019 - Elsevier
We explored the mechanisms governing the selectivity of anion-and cation-exchange
membranes for the transport of four monovalent anions (ie, fluoride, chloride, bromide, and …

Comparison of ion selectivity in electrodialysis and capacitive deionization

AN Shocron, RS Roth, EN Guyes… - … & Technology Letters, 2022 - ACS Publications
Ion-selective removal is an important frontier in water purification technologies. For many
emerging applications, removing all ions indiscriminately can lead to excessive energy …