Metallaphotoredox: the merger of photoredox and transition metal catalysis
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
The merger of transition metal and photocatalysis
The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …
has recently emerged as a versatile platform for the development of new, highly enabling …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis
F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …
reactivity of these compounds in organic synthesis has been historically overlooked. The …
Visible‐light‐induced organic photochemical reactions through energy‐transfer pathways
QQ Zhou, YQ Zou, LQ Lu… - Angewandte Chemie …, 2019 - Wiley Online Library
Visible‐light photocatalysis is a rapidly develo** and powerful strategy to initiate organic
transformations, as it closely adheres to the tenants of green and sustainable chemistry …
transformations, as it closely adheres to the tenants of green and sustainable chemistry …
Visible‐light‐induced homolysis of earth‐abundant metal‐substrate complexes: A complementary activation strategy in photoredox catalysis
The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …
Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis
A Hu, JJ Guo, H Pan, Z Zuo - Science, 2018 - science.org
With the recent soaring production of natural gas, the use of methane and other light
hydrocarbon feedstocks as starting materials in synthetic transformations is becoming …
hydrocarbon feedstocks as starting materials in synthetic transformations is becoming …
Metallaphotoredox catalysis for sp 3 C–H functionalizations through hydrogen atom transfer (HAT)
J Zhang, M Rue** - Chemical Society Reviews, 2023 - pubs.rsc.org
In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …
Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling
Conspectus In recent years, the development of light-driven reactions has contributed
numerous advances in synthetic organic chemistry. A particularly active research area …
numerous advances in synthetic organic chemistry. A particularly active research area …
Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals
Here we report the development of a C (sp3)–H cross-coupling platform enabled by the
catalytic generation of chlorine radicals by nickel and photoredox catalysis. Aryl chlorides …
catalytic generation of chlorine radicals by nickel and photoredox catalysis. Aryl chlorides …