Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

LK Macreadie, KB Idrees, CS Smoljan… - Angewandte …, 2023 - Wiley Online Library
Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas,
which are acquiring rapid attention on an exponential basis. A significant characteristic of …

Recent progresses on metal-organic frameworks for separation of gaseous hydrocarbons

JH Li, JX Chen, RB Lin, XM Chen - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Separation of gaseous hydrocarbons gets involved in many important industrial processes
for manufacturing chemicals, polymers, plastics and fuels, which are performed through …

Self-Healing B← N-Based Hydrogen-Bonded Organic Framework for Exclusive Recognition and Separation of Toluene from Methyl-Cyclohexane

Y Li, H Chen, J Huang, H Zhang, S Lin… - Journal of the …, 2024 - ACS Publications
The effective separation of aromatic and aliphatic hydrocarbons remains a notable
challenge in the petrochemical industry. Herein, we report a self-healing three-dimensional …

Robust carborane-based metal–organic frameworks for hexane separation

KB Idrees, KO Kirlikovali, C Setter, H **e… - Journal of the …, 2023 - ACS Publications
Hexane isomers play a vital role as feedstocks and fuel additives in the petrochemical
industry. However, their similar physical and chemical properties lead to significant …

Pore Chemistry and Architecture Control in Anionic Functional Ultramicroporous Materials for Record Dense Packing of Xenon

X Zhu, T Ke, P Han, Z Zhang, Z Bao… - Journal of the …, 2024 - ACS Publications
Adsorptive separation of Xe and Kr is an industrially promising but challenging process
because of their identical shape and similar physicochemical properties. Herein, we …

Pore Aperture Control Toward Size‐Exclusion‐Based Hydrocarbon Separations

B Lal, KB Idrees, H **e, CS Smoljan… - Angewandte …, 2023 - Wiley Online Library
Metal–organic frameworks (MOFs) have been proposed as a promising material for non‐
thermal chemical separations owing to their high structural diversity and tunability. Here, we …

Combination of Low-Polar and Polar Binding Sites in Aliphatic MOFs for the Efficient C2H6/C2H4 Separation

J Zhou, T Ke, X Zhu, B **, Z Bao, Z Zhang… - … Applied Materials & …, 2023 - ACS Publications
The selective capture of C2H6 from C2H6/C2H4 mixtures is of critical importance to realize
the efficient one-step purification of C2H4 but remains challenging due to their similar …

Selective Separation of C8 Aromatics by an Interpenetrating Metal–Organic Framework Material

N Sun, X Zhou, H Yu, X Si, F Ding, Y Sun… - Inorganic …, 2024 - ACS Publications
O-xylene (OX) is an important chemical raw material, but it is often produced in mixtures with
other C8 aromatics. Similar physicochemical properties of the C8 isomers make their …

High-capacity dynamic exclusion for highly efficient dilute C2H2 separation from CO2 and multicomponent mixture in robust ultramicroporous MOF by topology …

T Ke, Q Wang, X Zhu, J Hu, Z Bao, Z Zhang… - Chemical Engineering …, 2023 - Elsevier
Acquiring high C 2 H 2 adsorption capacity and effectively separating it from the most difficult-
to-separate byproduct CO 2 in a dilute state are crucial for obtaining high productivity/purity …

Polypyrene porous organic framework for efficiently capturing electron specialty gases

W Zhang, Y Li, Y Wu, W Huang, S Wang… - … Applied Materials & …, 2023 - ACS Publications
The polypyrene polymer with an extended π-conjugated skeleton is attractive for
perfluorinated electron specialty gas (F-gas) capture as the high electronegativity of fluorine …