Chemical fixation and conversion of CO2 into cyclic and cage-type metal carbonates

K Sołtys-Brzostek, M Terlecki, K Sokołowski… - Coordination Chemistry …, 2017 - Elsevier
Abstract Analysis of the Cambridge Structural Database (CSD) revealed over 1200 metal
carbonate compounds. At least 130 of them can be described as molecular mono-or …

A Giant Dy76 Cluster: A Fused Bi‐Nanopillar Structural Model for Lanthanide Clusters

XY Li, HF Su, QW Li, R Feng, HY Bai… - Angewandte Chemie …, 2019 - Wiley Online Library
Although great achievements have been made in the synthesis of giant lanthanide clusters,
novel structural models are still scarce. Herein, we report a giant lanthanide cluster Dy76 …

High-nuclearity silver clusters templated by carbonates generated from atmospheric carbon dioxide fixation

SD Bian, JH Jia, QM Wang - Journal of the American Chemical …, 2009 - ACS Publications
Two high-nuclearity silver clusters have been prepared by reacting AgC2Bu t with AgBF4 (or
AgOTf) in the presence of TMEDA in air. The reaction takes up atmospheric CO2 to give …

The crucial role of polyatomic anions in molecular architecture: structural and magnetic versatility of five nickel (II) complexes derived from AN, N, O-donor schiff base …

P Mukherjee, MGB Drew, CJ Gomez-Garcia… - Inorganic …, 2009 - ACS Publications
Five new nickel (II) complexes [Ni2L2 (N3) 2 (H2O) 2](1),[Ni2L2 (NO3) 2](2),[Ni2L2
(O2CPh)(CH3OH) 2] ClO4. 0.5 CH3OH (3),[Ni3L2 (O2CPh) 4](4), and [Ni2L2 (NO2) 2] n (5) …

Chemical fixation of atmospheric CO 2 in tricopper (ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and …

NC Jana, YC Sun, R Herchel, R Nandy… - Dalton …, 2024 - pubs.rsc.org
In the present era, the fixation of atmospheric CO2 is of significant importance and plays a
crucial role in maintaining the balance of carbon and energy flow within ecosystems …

Simultaneous self-assembly of a cage-like silver (I) complex encapsulating an Ag 6 neutral cluster core and carbon dioxide fixation

D Sun, GG Luo, N Zhang, RB Huang… - Chemical …, 2011 - pubs.rsc.org
A novel mixed-valent AgI/Ag0Th-Ag34 cage was obtained by a one-pot ultrasonic reaction.
In the shell of the cage, CO32− anion is derived from atmospheric CO2 and adopts a rare μ6 …

Structures and Magnetic Properties of Carbonato-Bridged Hexanuclear NiII4LnIII2 (Ln = Gd, Tb, Dy) Complexes Formed by Atmospheric Carbon Dioxide Fixation in …

S Maity, TK Ghosh, S Ito, P Bhunia, T Ishida… - Crystal Growth & …, 2022 - ACS Publications
The reaction of the mononuclear Ni (II) building block [NiL] of an asymmetrically
dicondensed N2O3 donor Schiff base ligand, N-salicylidene-N′-3-methoxysalicylidene-1, 3 …

(Ni2), (Ni3), and (Ni2 + Ni3): A Unique Example of Isolated and Cocrystallized Ni2 and Ni3 Complexes

P Mukherjee, MGB Drew, CJ Gómez-García… - Inorganic …, 2009 - ACS Publications
Structural and magnetic characterization of compound {[Ni2 (L) 2 (OAc) 2][Ni3 (L) 2 (OAc)
4]}· 2CH3CN (3)(HL= the tridentate Schiff base ligand, 2-[(3-methylamino-propylimino) …

Inclusion of Ln(III) in the Complexes of Co(II) with a Mannich Base Ligand: Development of Atmospheric CO2 Fixation and Enhancement of Catalytic Oxidase …

A Das, S Goswami, R Sen, A Ghosh - Inorganic Chemistry, 2019 - ACS Publications
The reaction of the Mannich base ligand (H2L= N, N′-dimethyl-N, N′-bis (2-hydroxy-3-
methoxy-5-methylbenzyl) ethylenediamine) with Co (OAc) 2· 4H2O and Ln (III) nitrate salts …

A Ferromagnetic Methoxido-Bridged Mn(III) Dimer and a Spin-Canted Metamagnetic μ1,3-Azido-Bridged Chain

S Naiya, S Biswas, MGB Drew… - Inorganic …, 2012 - ACS Publications
Two new Mn (III) complexes of formulas [MnL1 (N3)(OMe)] 2 (1) and [MnL2 (N3) 2] n (2)
have been synthesized by using two tridentate NNO-donor Schiff base ligands HL1 {(2-[(3 …