Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Remarkable advances and current state-of-the-art developments in catalytic
hydrophosphination of alkenes and alkynes are reviewed. The challenges in constructing a …

P‐stereogenic tert‐and sec‐phosphines have wide applications in asymmetric catalysis,
materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a …

A copper (I)-catalyzed asymmetric alkylation of HPAr1Ar2 with alkyl halides is uncovered,
which provides an array of P-stereogenic phosphines in generally high yield and …

The synthesis of phosphorus molecules presenting a chiral center on the P‐atom, also
known as P‐stereogenic compounds, has long attracted the curiosity of the scientific …

Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …

Abstract Herein, a copper (I)‐catalyzed asymmetric hydrophosphination of 3, 3‐disubstituted
cyclopropenes is reported. It provides a series of phosphine derivatives in high to excellent …

A palladium‐catalyzed enantioselective C H arylation of N‐(o‐bromoaryl)‐
diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a …

Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis
of Chiral Phosphines | Journal of the American Chemical Society ACS ACS Publications C&EN …

Chiral phosphanes, important ligands for metal‐catalyzed asymmetric syntheses, are often
prepared with compounds from the chiral pool, by using stoichiometric chiral auxiliaries, or …