EPR spectroscopy: A versatile tool for exploring transition metal complexes in organometallic and bioinorganic chemistry
M Ju, J Kim, J Shin - Bulletin of the Korean Chemical Society, 2024 - Wiley Online Library
Paramagnetic molecules, such as main‐group radicals and transition metal complexes, play
crucial roles in catalytic and enzymatic reactions in organometallic and bioinorganic …
crucial roles in catalytic and enzymatic reactions in organometallic and bioinorganic …
Single electron reduction of NHC–CO 2–borane compounds
A Morales, C Gonçalves, A Sournia-Saquet… - Chemical …, 2024 - pubs.rsc.org
The carbon dioxide radical anion [CO2˙−] is a highly reactive species of fundamental and
synthetic interest. However, the direct one-electron reduction of CO2 to generate [CO2˙−] …
synthetic interest. However, the direct one-electron reduction of CO2 to generate [CO2˙−] …
Highly Stable Self‐Regenerating Organic Multi‐Redox Systems derived from Bicyclic (Alkyl)(amino) carbenes (BICAACs)
An extended class of organic multi‐redox systems was derived from bicyclic (alkyl) amino
carbenes (BICAACs). The highly‐conjugated system undergoes a total of 4 redox events …
carbenes (BICAACs). The highly‐conjugated system undergoes a total of 4 redox events …
Synthesis of sterically congested unsymmetrical 1, 2-dicarbonyl radicals through a stepwise approach
A simplified and stepwise synthetic method for producing sterically congested
unsymmetrical 1, 2-dicarbonyl radicals was successfully demonstrated including detailed …
unsymmetrical 1, 2-dicarbonyl radicals was successfully demonstrated including detailed …
IZCp and PZCp: Redox Non-innocent Cyclopentadienyl Ligands as Electron Reservoirs for Sandwich Complexes
A long-sustained effort of systematic steric and electronic modification of cyclopentadienyl
(Cp) ligands has enabled them to find wide-ranging, valuable applications. Herein, we …
(Cp) ligands has enabled them to find wide-ranging, valuable applications. Herein, we …