Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

Fundamental and solutions of microcrack in Ni-rich layered oxide cathode materials of lithium-ion batteries

S Yin, W Deng, J Chen, X Gao, G Zou, H Hou, X Ji - Nano Energy, 2021 - Elsevier
Ni-rich layered transition metal oxide is one of the most promising cathode materials for the
next generation lithium-based automotive batteries due to its excellent electrochemical …

Controllable Cathode–Electrolyte Interface of Li[Ni0.8Co0.1Mn0.1]O2 for Lithium Ion Batteries: A Review

H Maleki Kheimeh Sari, X Li - Advanced Energy Materials, 2019 - Wiley Online Library
As a high‐capacity layered cathode material, Li [Ni0. 8Co0. 1Mn0. 1] O2 (NCM811) has
been one of the most felicitous candidates for utilization in the next generation of high …

In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal–Organic Frameworks to Design Atomic Co1–P1N3 Interfacial Structure for Promoting …

J Wan, Z Zhao, H Shang, B Peng, W Chen… - Journal of the …, 2020 - ACS Publications
The engineering coordination environment offers great opportunity in performance tunability
of isolated metal single-atom catalysts. For the most popular metal–N x (MN x) structure, the …

Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials

J Lee, DA Kitchaev, DH Kwon, CW Lee, JK Papp… - Nature, 2018 - nature.com
There is an urgent need for low-cost, resource-friendly, high-energy-density cathode
materials for lithium-ion batteries to satisfy the rapidly increasing need for electrical energy …

Layered Cathode Materials for Lithium-Ion Batteries: Review of Computational Studies on LiNi1–xyCoxMnyO2 and LiNi1–xyCoxAlyO2

A Chakraborty, S Kunnikuruvan, S Kumar… - Chemistry of …, 2020 - ACS Publications
At present the most successful rechargeable battery is the Li-ion battery, due to the small
size, high energy density, and low reduction potential of Li. Computational materials science …

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials

DH Seo, J Lee, A Urban, R Malik, SY Kang, G Ceder - Nature chemistry, 2016 - nature.com
Lithium-ion batteries are now reaching the energy density limits set by their electrode
materials, requiring new paradigms for Li+ and electron hosting in solid-state electrodes …

Narrowing the gap between theoretical and practical capacities in Li‐ion layered oxide cathode materials

MD Radin, S Hy, M Sina, C Fang, H Liu… - Advanced Energy …, 2017 - Wiley Online Library
Although layered lithium oxides have become the cathode of choice for state‐of‐the‐art Li‐
ion batteries, substantial gaps remain between the practical and theoretical energy …

Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides

J Hong, WE Gent, P **ao, K Lim, DH Seo, J Wu… - Nature materials, 2019 - nature.com
Reversible high-voltage redox chemistry is an essential component of many electrochemical
technologies, from (electro) catalysts to lithium-ion batteries. Oxygen-anion redox has …

Synchrotron X-ray analytical techniques for studying materials electrochemistry in rechargeable batteries

F Lin, Y Liu, X Yu, L Cheng, A Singer… - Chemical …, 2017 - ACS Publications
Rechargeable battery technologies have ignited major breakthroughs in contemporary
society, including but not limited to revolutions in transportation, electronics, and grid energy …