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Anion⋯ anion self-assembly under the control of σ-and π-hole bonds
The electrostatic attraction between charges of opposite signs and the repulsion between
charges of the same sign are ubiquitous and influential phenomena in recognition and self …
charges of the same sign are ubiquitous and influential phenomena in recognition and self …
Yet another perspective on hole interactions
Hole interactions are known by different names depending on the key atom of the bond
(halogen bond, chalcogen bond, hydrogen bond, etc.), and the geometry of the interaction (σ …
(halogen bond, chalcogen bond, hydrogen bond, etc.), and the geometry of the interaction (σ …
Anion⋅⋅⋅ Anion Interactions Involving σ‐Holes of Perrhenate, Pertechnetate and Permanganate Anions
In this communication experimental and theoretical results are reported affording strong
evidence that interactions between electron rich atoms and the metal of tetroxide anions of …
evidence that interactions between electron rich atoms and the metal of tetroxide anions of …
Anion⋅⋅⋅ anion coinage bonds: the case of tetrachloridoaurate
Interactions in crystalline tetrachloridoaurates of acetylcholine and dimethylpropiothetine are
characterized by Au⋅⋅⋅ Cl and Au⋅⋅⋅ O short contacts. The former interactions assemble …
characterized by Au⋅⋅⋅ Cl and Au⋅⋅⋅ O short contacts. The former interactions assemble …
Chalcogen and Hydrogen Bond Team up in Driving Anion⋅⋅⋅ Anion Self‐Assembly
Abstract H‐selenite anions (HSeO3−) form in the solid unprecedented anionic
supramolecular chains wherein single units are assembled via alternating short Se⋅⋅⋅ O …
supramolecular chains wherein single units are assembled via alternating short Se⋅⋅⋅ O …
Anion⋯ anion (MX 3−) 2 dimers (M= Zn, Cd, Hg; X= Cl, Br, I) in different environments
The possibility that MX3− anions can interact with one another is assessed via ab initio
calculations in gas phase as well as in aqueous and ethanol solution. A pair of such anions …
calculations in gas phase as well as in aqueous and ethanol solution. A pair of such anions …
[HTML][HTML] Anion–anion interactions in aerogen-bonded complexes. Influence of solvent environment
Ab initio calculations are applied to the question as to whether a AeX5− anion (Ae= Kr, Xe)
can engage in a stable complex with another anion: F−, Cl−, or CN−. The latter approaches …
can engage in a stable complex with another anion: F−, Cl−, or CN−. The latter approaches …
Anions as Lewis Acids in Noncovalent Bonds
S Scheiner - Chemistry–A European Journal, 2024 - Wiley Online Library
The ability of an anion to serve as electron‐accepting Lewis acid in a noncovalent bond is
assessed via DFT calculations. NH3 is taken as the common base, and is paired with a host …
assessed via DFT calculations. NH3 is taken as the common base, and is paired with a host …
Can H2 be Superacidic? A Computational Study of Triel-Bonded Brønsted Acids
J Brzeski - The Journal of Physical Chemistry A, 2024 - ACS Publications
The abundance of XIII group element compounds in science and industry together with their
electron-deficient character gives rise to their influence on properties of the systems they …
electron-deficient character gives rise to their influence on properties of the systems they …
Experimental and theoretical evidence of attractive interactions between dianions:[PdCl 4] 2−⋯[PdCl 4] 2−
Inspection of the arrangement of tetrachloridopalladate (II) centers in a crystalline solid
places the Cl of one [PdCl4] 2− directly above the Pd center of its neighbor. A survey of the …
places the Cl of one [PdCl4] 2− directly above the Pd center of its neighbor. A survey of the …