In his seminal work, 1 Rolf Huisgen defined 1, 3-dipolar cycloadditions as “1, 3-Dipole, abc,
must be defined, such that atom a posseses an electron sextet, that is, an incomplete …

Azomethine imines are considered 1, 3-dipoles of the aza-allyl type which are transient
intermediates and should be generated in situ but can also be stable and isolable …

The preparation of chiral compounds is an important and challenging area of contemporary
synthetic organic chemistry. 1 The 1, 3-dipolar cycloaddition, also known as the Huisgen …

In this paper we describe the phosphine-catalyzed [3+ 2],[3+ 3],[4+ 3], and [3+ 2+ 3]
annulations of azomethine imines and allenoates. These processes mark the first use of …

The synthesis of silicon-stereogenic silanes is undoubtedly one of the most intriguing and
challenging aspects in organic chemistry and organosilicon chemistry and is neglected by …

The syntheses, spectroscopic characterizations, and fluorescence quenching efficiencies of
polymers and copolymers containing tetraphenylsilole-or silafluorene-vinylene repeat units …

N-Heterocyclic carbenes derived from N-mesityl benzimidazolium salts are effective
catalysts for generating homoenolate species from α, β-unsaturated aldehydes. The …

A yet-unexploited class of azomethine imines, C, N-cyclic azomethine imines, could be
successfully employed in highly enantioselective 1, 3-dipolar cycloaddition with enals …

A titanium BINOLate catalyzed asymmetric 1, 3-dipolar cycloaddition reaction between α-
substituted acroleins and alkyl diazoacetates has been developed. With this methodology in …

Oompa loompa: The title reaction has been accomplished with high stereoselectivity by use
of an axially chiral dicarboxylic acid (see scheme). Employment of vinylogous aza …