Ligands for f-element extraction used in the nuclear fuel cycle
Liquid–liquid extraction is the major technique being applied for the partitioning of f-
elements from nuclear waste. In this review, the recent developments in ligand design …
elements from nuclear waste. In this review, the recent developments in ligand design …
Development of targeted alpha particle therapy for solid tumors
Targeted alpha-particle therapy (TAT) aims to selectively deliver radionuclides emitting α-
particles (cytotoxic payload) to tumors by chelation to monoclonal antibodies, peptides or …
particles (cytotoxic payload) to tumors by chelation to monoclonal antibodies, peptides or …
Pillararenes as macrocyclic hosts: a rising star in metal ion separation
L Chen, Y Cai, W Feng, L Yuan - Chemical Communications, 2019 - pubs.rsc.org
Pillararenes are macrocyclic oligomers of alkoxybenzene akin to calixarenes but tethered at
the 2, 5-positions via methylene bridges. Benefiting from their unique pillar-shaped …
the 2, 5-positions via methylene bridges. Benefiting from their unique pillar-shaped …
Recent progress in trivalent actinide and lanthanide solvent extraction and coordination chemistry with triazinylpyridine N donor ligands
A Geist, PJ Panak - Solvent Extraction and Ion Exchange, 2021 - Taylor & Francis
ABSTRACT A follow up to an earlier review on the coordination and extraction of trivalent
actinide and lanthanide ions with triazinylpyridine N-donor ligands is presented. It reviews …
actinide and lanthanide ions with triazinylpyridine N-donor ligands is presented. It reviews …
Supramolecular ligands for the extraction of lanthanide and actinide ions
EJ Werner, SM Biros - Organic Chemistry Frontiers, 2019 - pubs.rsc.org
Interest in the isolation and recovery of lanthanide and actinide metals has gained recent
attention due to their increasing use in everyday materials (eg batteries, screens, sensors) …
attention due to their increasing use in everyday materials (eg batteries, screens, sensors) …
Strong periodic tendency of trivalent lanthanides coordinated with a phenanthroline-based ligand: cascade countercurrent extraction, spectroscopy, and …
XF Yang, P Ren, Q Yang, JS Geng, JY Zhang… - Inorganic …, 2021 - ACS Publications
Phenanthroline-diamide ligands have been reported in the selective separation of actinides
over Eu (III); on the contrary, relevant basic coordination chemistry studies are still limited …
over Eu (III); on the contrary, relevant basic coordination chemistry studies are still limited …
The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation–a …
Theoretical calculations (density functional theory with the scalar relativistic ZORA
Hamiltonian) have been performed to obtain the energy and Gibbs free energy of formation …
Hamiltonian) have been performed to obtain the energy and Gibbs free energy of formation …
Selective Liquid–Liquid Extraction of Thorium (IV) from Rare-Earth Element Mixtures
WB Larrinaga, BJ Lake, VD Pacanowski… - Inorganic …, 2024 - ACS Publications
One of the major challenges in processing rare-earth element (REE) materials arises from
the large amounts of radioactive thorium (Th) that are often found within REE minerals …
the large amounts of radioactive thorium (Th) that are often found within REE minerals …
Selective Separation of Americium (III), Curium (III), and Lanthanide (III) by Aqueous and Organic Competitive Extraction
Q Wu, H Hao, Y Liu, LT Sha, WJ Wang, W Shi… - Inorganic …, 2023 - ACS Publications
Adding hydrophilic ligands into aqueous solutions for the selective binding of actinides (III) is
acknowledged as an advanced strategy in Ln (III)/An (III) separation. In view of the recycling …
acknowledged as an advanced strategy in Ln (III)/An (III) separation. In view of the recycling …
Selectivity of azine ligands toward lanthanide (III)/actinide (III) differentiation: A relativistic DFT based rationalization
Polyazines emerge as highly selective ligands toward actinide versus lanthanide
separation. Electronic structures of several mono-and polyazine f-complexes of general …
separation. Electronic structures of several mono-and polyazine f-complexes of general …