Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a
major challenge still remains: very few boron-centered nucleophiles exist for the direct …

Lewis base adducts of tetra‐alkoxy diboron compounds, in particular bis (pinacolato)
diboron (B2pin2), have been proposed as the active source of nucleophilic boryl species in …

One of the most recent advances of organoboron chemistry is the isolation and synthetic
applications of anionic sp2 boron nucleophiles with sensitive carbene-type structures [1](I …

N-Heterocyclic carbenes (NHCs) are widely used ligands and reagents in modern inorganic
synthesis as well as in homogeneous catalysis and organocatalysis. However, NHCs are …

Boron compounds have been traditionally regarded as “Lewis acids” preferring to accept
electrons rather than donate them in the course of their reactions but current examples of …

A palladium-catalyzed dearomative arylborylation of indoles is reported, which provides
straightforward access to structurally diverse indolines bearing vicinal tetrasubstituted and …

The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …