Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

Nowadays, there is much research focused on advanced technologies for energy storage
and conversion in order to mitigate environmental pollution and address concerns on future …

Oxidative dehydrogenation of propane (ODHP) is a key technology for producing propene
from shale gas, but conventional metal oxide catalysts are prone to overoxidation to form …

Nitrous oxide (N2O) decomposition is increasingly acknowledged as a viable strategy for
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …

When metals in supported catalysts are atomically dispersed, they are usually cationic and
bonded chemically to supports. Investigations of noble metals in this class are growing …

Although the tailored metal active sites and porous architectures of MOFs hold great promise
for engineering challenges ranging from gas separations to catalysis, a lack of …

The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Structural regulation of the active centers is often pivotal in controlling the catalytic functions,
especially in iron-based oxidation systems. Here, we discovered a significantly altered …

Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …