O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Gold-catalyzed carbon− heteroatom bond-forming reactions

A Corma, A Leyva-Pérez, MJ Sabater - Chemical reviews, 2011 - ACS Publications
After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …

Structure and surface chemistry of gold-based model catalysts

J Gong - Chemical reviews, 2012 - ACS Publications
Gold ([Xe] 4f 14 5d 10 6s 1) is one of the most ancient themes of investigation in science and
arts, and its renaissance now leads to an exponentially increasing number of publications …

Origin and activity of gold nanoparticles as aerobic oxidation catalysts in aqueous solution

C Shang, ZP Liu - Journal of the American Chemical Society, 2011 - ACS Publications
Whether gold is catalytically active on its own has been hotly debated since the discovery of
gold-based catalysis in the 1980s. One of the central controversies is on the O2 activation …

Toluene and 2-propanol mixture oxidation over Mn2O3 catalysts: Study of inhibition/promotion effects by in-situ DRIFTS

EJ Moreno-Román, J González-Cobos… - Chemical Engineering …, 2023 - Elsevier
Three Mn 2 O 3 catalysts were synthetized by different methods, characterized and tested in
toluene and 2-propanol (iPrOH) oxidation in single and binary component mixture. In single …

MnOx catalysts supported on SBA-15 and MCM-41 silicas for a competitive VOCs mixture oxidation: In-situ DRIFTS investigations

EJ Moreno-Román, F Can, V Meille… - Applied Catalysis B …, 2024 - Elsevier
The catalytic oxidation of different volatile organic compounds (VOCs) has been widely
studied for several decades within the field of air depollution. However, there is still much to …

The mystery of gold's chemical activity: local bonding, morphology and reactivity of atomic oxygen

TA Baker, X Liu, CM Friend - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
Recently, gold has been intensely studied as a catalyst for key synthetic reactions. Gold is
an attractive catalyst because, surprisingly, it is highly active and very selective for partial …

Oxidative dehydrogenation of ethanol on gold: Combination of kinetic experiments and computation approach to unravel the reaction mechanism

E Behravesh, MM Melander, J Wärnå, T Salmi… - Journal of …, 2021 - Elsevier
Selective alcohol dehydrogenation on heterogeneous catalysts is a key industrial reaction
for production of aldehydes, ketones, and carboxylic compounds. Design of catalysts with …

[HTML][HTML] Oxidative dehydrogenation of alcohols on gold: An experimental and computational study on the role of water and the alcohol chain length

L Mastroianni, T Weckman, K Eränen, V Russo… - Journal of …, 2023 - Elsevier
The oxidative dehydrogenation of primary alcohols promoted by gold nanoparticles was
investigated from an experimental and computational viewpoint to derive a plausible …

Low-temperature hydrogenation of acetaldehyde to ethanol on H-precovered Au (111)

M Pan, DW Flaherty, CB Mullins - The Journal of Physical …, 2011 - ACS Publications
Gold-based classical high surface area catalysts have been widely investigated for
hydrogenation reactions, but fundamental studies on model catalysts are lacking. We …