We begin by reviewing the early developments in the synthesis of high-spin organic
molecules and the simultaneous rationalization of the ground states of high spin. A number …

In this review, rational design strategies for pure organic high‐spin molecules with strong
intramolecular magnetic interactions are presented, mostly focusing on the design of …

A series of nitronyl nitroxide (NN) diradicals with linear conjugated couplers and another
series with aromatic couplers have been investigated by the broken-symmetry (BS) DFT …

The intramolecular magnetic coupling constant (J) values of diradical systems linked with
two monoradicals through a coupler (para-substituted phenyl acetylene (Model I), meta …

The stable organic diradicals that exhibit strong intramolecular ferromagnetic exchange
interactions are suitable building blocks for organic magnetic materials (OMMs). Based on …

The intramolecular magnetic coupling constant (J) values of sets of diradicals linked to bis-
DTDA, OVER, and NN radicals (DTDA, OVER, and NN groups) through an aromatic coupler …

Organic materials with extraordinary magnetic properties promise a wide range of light,
flexible, and inexpensive alternatives to familiar metal-based magnets. Individual organic …

In the quest of obtaining organic molecular magnets based on stable diradicals, we have
tuned the inherent zwitterionic ground state of tetraphenylhexaazaanthracene (TPHA), a …

The intramolecular magnetic coupling constants (J) of 9 diradicals (i–ix) coupled with an
aromatic ring were investigated by means of unrestricted density functional theory (DFT) …

A novel nitronyl nitroxide diradical based on the pyrazine ring, BNITPz (1, BNITPz= 2, 2′-(3,
6-dimethylpyrazine-2, 5-diyl) bis (1-hydroxy-4, 4, 5, 5-tetramethyl-4, 5-dihydro-1H-imidazole …