Conspectus Electrostatic interactions are ubiquitous in catalytic systems and can be decisive
in determining the reactivity and stereoselectivity. However, difficulties quantifying the role of …

We report herein a Cu‐catalyzed regio‐, diastereo‐and enantioselective acylboration of 1, 3‐
butadienylboronate with acyl fluorides. Under the developed conditions, the reactions …

As an essential van der Waals interaction, the dispersion interaction is an important weak
attractive interaction. However, the influence of the weak attractive interactions has only …

The catalytic performance of supported metal catalysts is closely related to their structure.
While Pt-based catalysts are widely used in many catalytic reactions because of their …

The formation of Brønsted acid aggregates in the course of asymmetric organocatalytic
reactions is often overlooked in mechanistic studies, even though it might have a deep …

Stereo-and enantioselective syntheses of 1, 2-oxaborinan-3-enes and δ-boryl-substituted
homoallylic alcohols are reported. We developed a practical approach to synthesize α-boryl …

Reported here is an iridium-catalyzed enantio-divergent C (sp3)-H borylation of α-gem-
dimethyl groups of trifluoromethyl ketone-derived hydrazones to construct a series of acyclic …

A Brønsted acid-catalyzed enantioselective synthesis of (Z)-1, 3-butadienyl-2-carbinols is
developed. By employing a chiral phosphoric acid as the catalyst, a variety of 1, 3-butadienyl …

Highly stereo-and enantioselective synthesis of δ-alkyl-substituted (Z)-homoallylic alcohols
via asymmetric allylation is developed. In the presence of a chiral phosphoric acid catalyst …

We report herein stereoselective syntheses of α, α-disubstituted (E)-and (Z)-crotylboronates.
Starting from α-boryl (E)-or (Z)-crotylboronate, base-mediated alkylation occurred …