Electrochemical water splitting is a mature technology for hydrogen generation. Numerous
studies have focused on the development of highly efficient electrocatalysts to produce …

Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Local electric fields can alter energy landscapes to impart enhanced reactivity in enzymes
and at surfaces. Similar fields can be generated in molecular systems using charged …

Transition metal nitrides have received considerable attention owing to their crucial roles in
nitrogen fixation and nitrogen atom transfer reactions. Compared to the early and middle …

Uranium nitride compounds are important molecular analogues of uranium nitride materials
such as UN and UN2 which are effective catalysts in the Haber–Bosch synthesis of …

Thorium nitrides are likely intermediates in the reported cleavage and functionalization of
dinitrogen by molecular thorium complexes and are attractive compounds for the study of …

The development of molecular species with switchable magnetic properties has been a long-
standing challenge in chemistry. One approach involves binding an analyte, such as …

In this computational study, the electronic structure changes along the oxidative and
reductive quenching cycles of a homoleptic and a heteroleptic prototype Cu (I) photoredox …

Despite their connection to ammonia synthesis, little is known about the ability of iron‐
bound, bridging nitrides to form N− H bonds. Herein we report a linear diiron bridging nitride …

Herein, we investigate the effects of ligand design on the nuclearity and reactivity of metal–
ligand multiply bonded (MLMB) complexes to access an exclusively bimetallic reaction …