Expanding the Chemistry of Molecular U2+ Complexes: Synthesis, Characterization, and Reactivity of the {[C5H3(SiMe3)2]3U} Anion

CJ Windorff, MR MacDonald… - … A European Journal, 2016 - Wiley Online Library
The synthesis of new molecular complexes of U2+ has been pursued to make comparisons
in structure, physical properties, and reactivity with the first U2+ complex,[K (2.2. 2 …

Organoactinide chemistry: synthesis and characterization

CJ Burns, MS Eisen - The Chemistry of the Actinide and Transactinide …, 2006 - Springer
The advent of modern organometallic chemistry has often been cited as the report of the
preparation of ferrocene,(η 5-C 5 H 5) 2 Fe, the first metallic complex containing a …

Syntheses, X‐Ray Crystal Structures, and Magnetic Properties of Novel Linear M _2^II UIV Complexes (M= Co, Ni, Cu, Zn)

T Le Borgne, E Rivière, J Marrot… - … A European Journal, 2002 - Wiley Online Library
Attempts to prepare heterobimetallic complexes in which 3d and uranium magnetic ions are
associated by means of the Schiff bases H2Li derived from 2‐hydroxybenzaldehyde or 2 …

Trimethylsilylcyclopentadienyl (Cp) Uranium Chemistry: Synthetic and Structural Studies of Cp4U and Cp3UX (X = Cl, I, Me)

CJ Windorff, MR MacDonald, JW Ziller… - … für anorganische und …, 2017 - Wiley Online Library
Cp′ 4U (Cp′= C5H4SiMe3) was synthesized from:(a) KCp′ and [Cp′ 3U
(THF)][BPh4];(b) Cp′ 3U and Cp′ 2Pb; and (c)[K (2.2. 2‐cryptand)][Cp′ 4U] and AgBPh4 …

Metalloligands containing samarium (III). Access to binuclear f-metal (samarium)-d-metal (rhodium) complexes

M Visseaux, A Dormond, MM Kubicki, C Moise… - Journal of …, 1992 - Elsevier
The synthesis of the new dimethylphosphinotetramethylcyclopentadi… HC 5 Me 4 PMe 2
and of its potassium salt KC 5 Me 4 PMe 2 are reported. Reactions of this potassium salt (as …

Synthesis and Small Molecule Reactivity of Uranium(IV) Alkoxide Complexes with both Bound and Pendant N‐heterocyclic Carbene Ligands

PL Arnold, AJ Blake, C Wilson - Chemistry–A European …, 2005 - Wiley Online Library
The syntheses of two tetravalent uranium alkoxide‐carbene complexes are reported,[UIL3],
and [UL4] where L= OCMe2CH2 [1‐C (NCHCHNiPr)]. The latter shows dynamic behaviour …

Synthesis of bis (diphenylphosphinocyclopentadienyl) yttrium chloride complexes and heterodimetallic derivatives. X-ray structure of bis [(μ-chloro) bis …

R Broussier, G Delmas, P Perron, B Gautheron… - Journal of …, 1996 - Elsevier
Reaction of lithium diphenylphosphinocyclopentadienide with YCl3 or YCl3 (THF) 3 and
working lead to the formation of three yttrocene phosphines: the lithium metal adduct …

Transition-metal derivatives of the functionalized cyclopentadienyl ligand. XVI. Synthesis of the bridged complexes [(µ-η5-C5H4PPh2) M (CO) 2] 2 (M= Cr, Mo, W). X …

B Brumas-Soula, F Dahan - New Journal of Chemistry, 1998 - pubs.rsc.org
5 H 4 PPh 2) M (CO) 2 H] 2 a result of the expected competition between the
dehydrogenation and the decarbonylation processes. The X-ray molecular structure of 7c …

Lanthanides and actinides annual survey covering the year 1990

RD Rogers, LM Rogers - Journal of organometallic chemistry, 1992 - Elsevier
Several reviews appeared in 1990 on specific synthetic aspects of organo-f-element
compounds. Deacon, et al. reviewed chemical vapor deposition of rare earth compounds in …

2 Allyl Complexes and Complexes Derived from Monoalkenes Cr, Mo and w

PK BAKER - Organometallic Chemistry: Volume 20, 2007 - books.google.com
The reaction of trans-[M (PMe3) 4 (n²-C2H4) 2](M= Mo or W) with CS₂ gave the head-to-tail
CS₂ dimers of [M (C₂S4)(PMе 3) 3 (n²− C₂H4)], one of which was structurally …