Advances in application of azobenzene as a trigger in biomedicine: Molecular design and spontaneous assembly

HB Cheng, S Zhang, J Qi, XJ Liang… - Advanced …, 2021 - Wiley Online Library
Azobenzene is a well‐known derivative of stimulus‐responsive molecular switches and has
shown superior performance as a functional material in biomedical applications. The results …

Azobenzene‐based photochromic delivery vehicles for ions and small molecules

M Sahid Hossain, S Chatterjee… - … –A European Journal, 2022 - Wiley Online Library
Molecular switches have been used as delivery vehicles for various molecular and ionic
species. The ones that reversibly operate with light are arguably the best candidates for the …

Fluorescent azobenzene-containing compounds: from structure to mechanism

L Xue, Y Pan, S Zhang, Y Chen, H Yu, Y Yang, L Mo… - Crystals, 2021 - mdpi.com
The reversible photoisomerization of azobenzenes has been extensively studied to
construct systems with optical responsiveness; however, this process limits the …

A Change of Pace: Record Photoresponse through Spirooxazine Confinement in a Metal–Organic Matrix

GC Thaggard, GR Wilson, M Naik… - Journal of the …, 2024 - ACS Publications
Modern and upcoming high-speed optoelectronics as well as secure data storage or solar
energy harvesting technologies integrating stimuli-responsive materials fully rely on the …

Synthesis of Halogenated Dibenzo [1, 2, 6] triazonines and Late-Stage Functionalization of the Triazonine Ring

V Delattre, N Goual, P Retailleau… - The Journal of …, 2024 - ACS Publications
Dibenzotriazonine represent a new class of nine-membered cyclic azobenzenes with a
nitrogen atom embedded in the bridging chain. To enable future applications of this …

Reversible photoresponsive activity of a carbonic anhydrase mimic

M Saha, S Bandyopadhyay - Chemical Communications, 2019 - pubs.rsc.org
The carbonic anhydrase (CA) enzyme reversibly transforms carbon dioxide and water to a
carbonate ion and a proton. Photoresponsive enzyme mimics, where the CA-activity can be …

Synthesis and Characterization of a [1, 2, 6] Diazaphosphonine Oxide: An Example of a Photoswitchable Phosphorus-Containing Cyclic Azobenzene

N Goual, S Maisonneuve, P Retailleau… - The Journal of …, 2024 - ACS Publications
We report herein the synthesis and characterization of a phosphorus-containing cyclic
azobenzene as a new photoswitchable scaffold. This backbone reveals high bidirectional …

Modulation of Electronic Mobility of a One‐Dimensional Coordination Polymeric Molecular Wire with Light

M Saha, S Chatterjee, MS Hossain… - Chemistry–An Asian …, 2019 - Wiley Online Library
Metal ions often influence the photoswitching efficiency of a photochromic system. This
article reports a one‐dimensional polymer having cyclic azobenzenes coordinated to silver …

Cyclic hybrid compounds based on 1, 3-and 1, 5-dichlorosiloxanes and 2, 2′-dihydroxyazobenzene

AS Soldatenko, NF Lazareva - Russian Chemical Bulletin, 2021 - Springer
The first representatives of cyclic azobenzene-siloxane hybrid compounds, namely, 2, 4-
dimethyl-2, 4-diorganyl-1, 3, 5-trioxa-8, 9-diaza-2, 4-disiladibenzo [f, j] cycloundecanes and …

Molecular Design of Silicon‐Containing Diazenes: Absorbance of E and Z Isomers in the Near‐Infrared Region

EP Doronina, V Jouikov… - Chemistry–A European …, 2022 - Wiley Online Library
The effective use of photochromic systems based on azo compounds in a number of
applications, especially biomedical and pharmacological ones, is impeded by the …