The synthesis of molecules that feature main-group elements in unusual oxidation states
and coordination environments is a primary pursuit of main-group chemistry. The p-block …

We report the synthesis and spectroscopic identification of the trisbenzene complexes of
strontium and barium M (Bz) 3 (M= Sr, Ba) in low‐temperature Ne matrix. Both complexes …

Low-valent group 2 (E= Be and Mg) stabilized compounds have been long synthetically
pursued. Here we discuss the electronic structure of a series of Lewis base-stabilized Be …

We discuss the fundamental aspects of the EDA-NOCV method and address some critical
comments that have been made recently. The EDA-NOCV method unlike most other …

Quantum chemical calculations using density functional theory are reported for the diatomic
molecules LiF, BeO, and BN. The nature of the interatomic interactions is analyzed with the …

Comment on “Realization of Lewis Basic Sodium Anion in the NaBH3− Cluster” - Pan - 2020 -
Angewandte Chemie - Wiley Online Library Skip to Article Content Skip to Article Information …

The preparation and spectroscopic identification of the complexes NNBe (η2‐N2) and (NN)
2Be (η2‐N2) and the energetically higher lying isomers Be (NN) 2 and Be (NN) 3 are …

We report a combined experimental and theoretical study on the first examples of
carbodicarbene (CDC)‐stabilized bismuth complexes, which feature low‐coordinate cationic …

Quantum chemical calculations of the alkaline‐earth oxides, imides and dihydrides of the
alkaline‐earth atoms (Ae= Be, Mg, Ca, Sr, Ba) and the calcium cluster Ca6H9 [N (SiMe3) 2] …

The CaCO2 complex is generated via the reaction of excited-state calcium atom with carbon
dioxide in a solid neon matrix. Infrared absorption spectroscopy and quantum chemical …