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Exploring and leveraging aggregation effects on reactive oxygen species generation in photodynamic therapy
Aggregate‐level photodynamic therapy (PDT) has attracted significant interest and driven
substantial advances in multifunction phototheranostic platforms. As exemplified by two …
substantial advances in multifunction phototheranostic platforms. As exemplified by two …
Ligand Exchange at Carbon: Synthetic Entry to Elusive Species and Versatile Reagents
F Krischer, VH Gessner - JACS Au, 2024 - ACS Publications
How different is carbon compared to other elements in the periodic table? Can carbon
compounds be regarded as coordination complexes with carbon as the central element …
compounds be regarded as coordination complexes with carbon as the central element …
Air-and photo-stable luminescent carbodicarbene-azaboraacenium ions
Substitution of a C= C bond by an isoelectronic B–N bond is a well-established strategy to
alter the electronic structure and stability of acenes. BN-substituted acenes that possess …
alter the electronic structure and stability of acenes. BN-substituted acenes that possess …
Redox-and Charge-State Dependent Trends in 5, 6, and 7-Membered Boron Heterocycles: A Neutral Ligand Coordination Chemistry Approach to Boracyclic Cations …
KK Hollister, KE Wentz… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Boron heterocycles represent an important subset of heteroatom-incorporated
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …
Lewis superacidic heavy pnictaalkene cations: comparative assessment of carbodicarbene-stibenium and carbodicarbene-bismuthenium ions
We report a comprehensive assessment of Lewis acidity for a series of carbone-stibenium
and-bismuthenium ions using the Gutmann–Beckett (GB) method. These new antimony and …
and-bismuthenium ions using the Gutmann–Beckett (GB) method. These new antimony and …
Synthesis, Characterization, and Properties of Three-Dimensional Analogues of 9-Borafluorenes
Three-dimensional (3D) analogues of 9-borafluorenes,(C2B10H10) 2BR (R= Cl (1), Br (2), H
(3, merely as ether or silane adduct), phenyl (4), mesityl (5)), were synthesized and fully …
(3, merely as ether or silane adduct), phenyl (4), mesityl (5)), were synthesized and fully …
Cleavage of Carbodicarbenes with N2O for Accessing Stable Diazoalkenes: Two‐Fold Ligand Exchange at a C(0)‐Atom
Y He, Y Lyu, D Tymann, PW Antoni… - Angewandte Chemie …, 2025 - Wiley Online Library
The cleavage of carbophosphinocarbenes and carbodicarbenes with nitrous oxide (N2O)
leads to the formation of room‐temperature stable diazoalkenes. The utility of Ph3P/N2 and …
leads to the formation of room‐temperature stable diazoalkenes. The utility of Ph3P/N2 and …
Synthesis and reactivity of an anionic diazoolefin
Bent (hetero) allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral
C‐donor ligands, and diverse applications in coordination chemistry have been reported. N …
C‐donor ligands, and diverse applications in coordination chemistry have been reported. N …
Solvatochromic and aggregation-induced emission active nitrophenyl-substituted pyrrolidinone-fused-1, 2-azaborine with a pre-twisted molecular geometry
AD Campbell, K Ellis, LK Gordon, JE Riley… - Journal of Materials …, 2023 - pubs.rsc.org
Boron–nitrogen-containing heterocycles with extended conjugated π-systems such as
polycyclic aromatic 1, 2-azaborines, hold the fascination of organic chemists due to their …
polycyclic aromatic 1, 2-azaborines, hold the fascination of organic chemists due to their …
Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand
B Kooij, DW Chen, F Fadaei‐Tirani… - Angewandte Chemie …, 2024 - Wiley Online Library
Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in
organometallic and main group element chemistry. Herein, we report a structurally distinct …
organometallic and main group element chemistry. Herein, we report a structurally distinct …