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Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Light-controlled radical polymerization: mechanisms, methods, and applications
The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …
strategy for rational polymer synthesis and advanced materials fabrication. This review …
Atom transfer radical polymerization: billion times more active catalysts and new initiation systems
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …
established as a powerful technique to prepare precisely defined polymeric materials. This …
Kinetics of atom transfer radical polymerization
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …
Translating Surface-Initiated Atom Transfer Radical Polymerization into Technology: The Mechanism of Cu0-Mediated SI-ATRP under Environmental Conditions
The exceptional features of Cu0-mediated surface-initiated atom transfer radical
polymerization (Cu0 SI-ATRP), and its potential for implementation in technologically …
polymerization (Cu0 SI-ATRP), and its potential for implementation in technologically …
The Role of Cu0 in Surface-Initiated Atom Transfer Radical Polymerization: Tuning Catalyst Dissolution for Tailoring Polymer Interfaces
The availability of catalytic/reducing sites at metallic Cu0 sources during supplemental
activator and reducing agent atom transfer radical polymerization (SARA ATRP) is regulated …
activator and reducing agent atom transfer radical polymerization (SARA ATRP) is regulated …
Radical generation and termination in SARA ATRP of methyl acrylate: effect of solvent, ligand, and chain length
Supplemental activator and reducing agent (SARA) ATRP is an efficient way to diminish the
amount of Cu catalyst. A kinetic study of radical generation and termination in SARA ATRP …
amount of Cu catalyst. A kinetic study of radical generation and termination in SARA ATRP …
Understanding the synthesis of linear–bottlebrush–linear block copolymers: toward plastomers with well-defined mechanical properties
Linear–bottlebrush–linear (LBL) triblock copolymers were synthesized via a two-step atom
transfer radical polymerization (ATRP):(i) grafting-through polymerization of …
transfer radical polymerization (ATRP):(i) grafting-through polymerization of …
Electron transfer reactions in atom transfer radical polymerization
Electrochemistry may seem an outsider to the field of polymer science and controlled radical
polymerization. Nevertheless, several electrochemical methods have been used to …
polymerization. Nevertheless, several electrochemical methods have been used to …
Detailed kinetic and mechanistic insight into radical polymerization by spectroscopic techniques
M Buback, H Schroeder, H Kattner - Macromolecules, 2016 - ACS Publications
The in-depth understanding of the kinetics and mechanism of conventional and reversible
deactivation radical polymerization (RDRP) strategies requires efficient techniques to attain …
deactivation radical polymerization (RDRP) strategies requires efficient techniques to attain …