On the versatility of urethane/urea bonds: reversibility, blocked isocyanate, and non-isocyanate polyurethane

E Delebecq, JP Pascault, B Boutevin… - Chemical …, 2013 - ACS Publications
Discovered by Wurtz in 1848, the isocyanates revealed their chemistry from systematic study
during the nineteenth century, for example, by Curtius or Hofmann. The discovery of …

Recycling of polyurethanes: where we are and where we are going

G Rossignolo, G Malucelli, A Lorenzetti - Green Chemistry, 2024 - pubs.rsc.org
Polyurethanes (PUs) represent a family of useful synthetic polymers (thermoplastic or
thermosetting) obtained from diisocyanates and diols/polyols via polycondensation …

Transcarbamoylation in polyurethanes: underestimated exchange reactions?

C Bakkali-Hassani, D Berne, V Ladmiral… - Macromolecules, 2022 - ACS Publications
While transesterification has been largely explored by chemists, only a few studies
comparatively dealt with its “sluggish cousin”, transcarbamoylation. Originally suggested 70 …

Recycling of polyurethanes from laboratory to industry, a journey towards the sustainability

D Simón, AM Borreguero, A De Lucas, JF Rodríguez - Waste Management, 2018 - Elsevier
The recycling of any kind of plastic to convert it in valuable products is one of the main
challenges of today's society. Besides, if the recycling process is itself green, then it would …

Insight into chemical recycling of flexible polyurethane foams by acidolysis

M Grdadolnik, A Drinčić, A Oreški… - ACS sustainable …, 2022 - ACS Publications
Acidolysis is emerging as a promising method for recycling polyurethane foam (PUF) waste.
Here, we present highly efficient acidolysis of PUFs with adipic acid (AA) by heating the …

Glycolysis: An efficient route for recycling of end of life polyurethane foams

R Heiran, A Ghaderian, A Reghunadhan… - Journal of Polymer …, 2021 - Springer
The increased applications of Polyurethane (PU) materials give rise to a higher amount of
wastes, which have a devastating effect on the earth in turn; therefore, the management of …

Polydiketoenamines for a circular plastics economy

BA Helms - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus The mismanagement and leakage of plastic waste into the environment are
failures of modern society. Once in the environment, plastic waste degrades into …

Variable amine spacing determines depolymerization rate in polydiketoenamines

AR Epstein, J Demarteau, BA Helms… - Journal of the …, 2023 - ACS Publications
The design of circular polymers has emerged as a necessity due to the lack of efficient
recycling methods for many commodity plastics, particularly those used in durable products …

Multistage chemical recycling of polyurethanes and dicarbamates: A glycolysis–hydrolysis demonstration

P Zahedifar, L Pazdur, CML Vande Velde, P Billen - Sustainability, 2021 - mdpi.com
The use of polyurethanes and, therefore, the quantity of its scrap are increasing.
Considering the thermoset characteristic of most polyurethanes, the most circular recycling …

tert-Amyl Alcohol-Mediated Deconstruction of Polyurethane for Polyol and Aniline Recovery

MB Johansen, BS Donslund… - ACS Sustainable …, 2022 - ACS Publications
Polyurethane (PU) is a highly engineered and cross-linked polymer found in a plethora of
materials such as mattresses, shoes, windmills, and insulation of refrigerating appliances …